(3aR,4S,7R,7aS)-2-Phenyl-4-propyl-3a,4,7,7a-tetrahydro-1H-4,7-epithioisoindole-1,3-dione 8-oxide

被引:2
作者
Demircan, Aydin [2 ]
Sahin, Ertan [3 ]
Beyazova, Gozde [2 ]
Karaaslan, Muhsin [4 ]
Hokelek, Tuncer [1 ]
机构
[1] Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey
[2] Nigde Univ, Dept Chem, TR-51100 Nigde, Turkey
[3] Ataturk Univ, Dept Chem, TR-25240 Erzurum, Turkey
[4] Aksaray Univ, Dept Chem, TR-68100 Aksaray, Turkey
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
DIELS-ALDER REACTION; THIOPHENE; 3,3-DIOXIDE;
D O I
10.1107/S1600536811012876
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the tetrahydroisoindole moiety of the title compound, C17H17NO3S, the six-membered ring assumes a boat configuration and the -S=O group bridges the prow and stern of the boat. The phenyl ring is oriented at a dihedral angle of 83.2 (1)degrees with respect to the pyrrole ring. In the crystal, intermolecular C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. A weak C-H center dot center dot center dot pi interaction involving the phenyl ring is also found. The crystal studied was an inversion twin.
引用
收藏
页码:O1085 / U1884
页数:12
相关论文
共 16 条
[1]   Reactivity of condensed thiophenes in the Diels-Alder reaction: The reactivity of 3-aminothieno[3,4:3',4'] benzo[b]pyranone; 3-aminothieno[3,4-c]qninoline and of 5-amino-7-substituted thieno[3,4-d]pyridazinone toward electron-poor olefins and acetylenes. [J].
AlOmran, F ;
Khalik, MMA ;
AlAwadhi, H ;
Elnagdi, MH .
TETRAHEDRON, 1996, 52 (36) :11915-11928
[2]  
Arslan H, 2007, ACTA CHIM SLOV, V54, P341
[3]   AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY [J].
BLESSING, RH .
ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :33-38
[4]  
Farrugia L.J., 1997, J. Appl. Crystallogr., V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]
[5]  
Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]
[6]   ON ENANTIOMORPH-POLARITY ESTIMATION [J].
FLACK, HD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881
[7]   5-chloro-10-oxa-3-thiatricyclo[5.2.1.01,5] dec-8-ene 3,3-dioxide [J].
Kosar, Basak ;
Gokturk, Ersen ;
Demircan, Aydin ;
Buyukgungor, Orhan .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 :O4192-O4193
[8]   DIELS-ALDER REACTION OF THIOPHENE WITH MALEIC-ANHYDRIDE AT VERY HIGH-PRESSURE [J].
KOTSUKI, H ;
KITAGAWA, S ;
NISHIZAWA, H ;
TOKOROYAMA, T .
JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (07) :1471-1472
[9]  
KUHN HJ, 1972, TETRAHEDRON LETT, P1909
[10]   MOLECULAR ORBITAL AND MAPPING STUDY OF ALLOWED DIELS-ALDER REACTIONS OF FURAN, THIOPHENE, AND THIOPHENE DIOXIDE [J].
LERT, PW ;
TRINDLE, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (24) :6392-&