Fe(OTf)3-Catalyzed Reaction of Benzylic Acetates with Organosilicon Compounds

被引：26

作者：

Chan, Li Yan ^{[1
]}

Kim, Sundae ^{[1
]}

Chung, Wan Ting ^{[1
]}

Long, Chong ^{[1
]}

Kim, Sunggak ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

SYNLETT | 2011年 / 03期

关键词：

iron-catalyzed reaction; allylation; azidation; cyanation; benzylic acetates; organosilanes; HETERO-MICHAEL ADDITION; BOND-FORMING REACTIONS; COUPLING REACTION; BISMUTH(III) CHLORIDE; INDIUM-TRICHLORIDE; EFFICIENT CATALYST; CARBONYL-COMPOUNDS; ALCOHOLS; ALLYLATION; ARYLATION;

D O I：

10.1055/s-0030-1259313

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Fe(OTf)(3)-catalyzed reaction of benzylic acetates with allyltrimethylsilane, azidotrimethylsilane, and cyanotrimethylsilane afforded the corresponding allylated, azido, and cyano products in high yields. 2-Trimethylsilyl-substituted benzofuran and indole worked well to furnish the benzyl-substituted benzofuran and indoles.

引用

页码：415 / 419

页数：5

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