The Effect of pH on OH Radical Generation in Aqueous Solutions by Atmospheric Pressure Glow Discharge

被引：34
作者：
Khlyustova, Anna [1 ]
Khomyakova, Natalija [2 ]
Sirotkin, Nikolaj [1 ]
Marfin, Yuriy [2 ]
机构：
[1] Russian Acad Sci, GA Krestov Inst Solut Chem, Lab Chem Carbohydrate Coordinat Cpds & Supermol S, Acad Skaja Str 1, Ivanovo 153045, Russia
[2] Ivanovo State Univ Chem & Technol, Dept Inorgan Chem, Sheremetevski Ave 7, Ivanovo 153000, Russia
来源：
PLASMA CHEMISTRY AND PLASMA PROCESSING | 2016年 / 36卷 / 05期
关键词：
OH radicals; Atmospheric pressure glow discharge; Formation rate; Yield; STREAMER CORONA DISCHARGE; HYDROXYL RADICALS; HYDRATED ELECTRONS; HYDROGEN-ATOMS; WATER; PLASMA; GAS; RADIOLYSIS; FERROCYANIDE; FERRICYANIDE;
D O I：
10.1007/s11090-016-9732-3
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Formation of hydroxyl radicals in aqueous solutions by atmospheric pressure DC glow discharge was investigated. The ferrocyanide was used as an OH scavenger at different pH. Experimental results indicated that pH effect on hydroxyl radical formation rate could be explained by particularities of [Fe(CN)(6)](4-) and reactive species interaction in different media.
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收藏
页码：1229 / 1238
页数：10
相关论文
共 46 条
[1]   SPECTROSCOPIC STUDIES OF REACTIONS OF OH RADICAL IN AQUEOUS SOLUTIONS [J].
ADAMS, GE ;
BOAG, JW ;
MICHAEL, BD .
TRANSACTIONS OF THE FARADAY SOCIETY, 1965, 61 (507P) :492-&
[2]  
[Anonymous], 1972, 1830172 GOST
[3]   PULSE RADIOLYTIC INDUCED TRANSIENT ELECTRICAL CONDUCTANCE IN LIQUID SOLUTIONS .2. RADIOLYSIS OF AQUEOUS SOLUTIONS OF NO-3, NO-2 AND FE(CN)3-/6 [J].
BARKER, GC ;
FOWLES, P ;
STRINGER, B .
TRANSACTIONS OF THE FARADAY SOCIETY, 1970, 66 (570) :1509-&
[4]   Formations of active species and by-products in water by pulsed high-voltage discharge [J].
Bian, Wenjuan ;
Zhou, Minghua ;
Lei, Lecheng .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 2007, 27 (03) :337-348
[5]   REACTIVITY OF HO2/O-2 RADICALS IN AQUEOUS-SOLUTION [J].
BIELSKI, BHJ ;
CABELLI, DE ;
ARUDI, RL ;
ROSS, AB .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1985, 14 (04) :1041-1100
[6]   Characteristics of atmospheric pressure air discharges with a liquid cathode and a metal anode [J].
Bruggeman, Peter ;
Ribezl, Eva ;
Maslani, Alan ;
Degroote, Joris ;
Malesevic, Alexander ;
Rego, Robby ;
Vierendeels, Jan ;
Leys, Christophe .
PLASMA SOURCES SCIENCE & TECHNOLOGY, 2008, 17 (02)
[7]   CRITICAL-REVIEW OF RATE CONSTANTS FOR REACTIONS OF HYDRATED ELECTRONS, HYDROGEN-ATOMS AND HYDROXYL RADICALS (.OH/.O-) IN AQUEOUS-SOLUTION [J].
BUXTON, GV ;
GREENSTOCK, CL ;
HELMAN, WP ;
ROSS, AB .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1988, 17 (02) :513-886
[8]  
Cserfalvi T, 1996, FRESEN J ANAL CHEM, V355, P813
[9]   GLOW-DISCHARGE ELECTROLYSIS IN AQUEOUS SOLUTIONS [J].
DENARO, AR ;
HICKLING, A .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1958, 105 (05) :265-270
[10]   GLOW-DISCHARGE ELECTROLYSIS OF ALKALINE FERROCYANIDE SOLUTIONS [J].
DENARO, AR ;
OWENS, PA .
ELECTROCHIMICA ACTA, 1968, 13 (02) :157-&
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