Tunable excitation-dependent-fluorescence of carbon dots: Fingerprint curves for super anti-counterfeiting

被引:40
作者
Cheng, Ke [1 ,2 ]
Qi, Rui [1 ,2 ]
Lan, Shuai [1 ]
Wang, Hongyang [1 ]
Zheng, Xuefang [1 ]
Liu, Chun [1 ]
Jia, Dandan [1 ]
Cao, Lei [1 ]
Wang, Dongjun [1 ,2 ]
机构
[1] Hebei Normal Univ Sci & Technol, Sch Chem Engn, 360 Hebei St, Qinhuangdao, Hebei, Peoples R China
[2] Hebei Normal Univ Sci & Technol, Ctr Anal & Measurement, 360 Hebei St, Qinhuangdao, Hebei, Peoples R China
关键词
Carbon dots; Excitation-dependent fluorescence; Concentration-dependent fluorescence; Anti-Counterfeiting; NONCONJUGATED POLYMER DOTS; LINK-ENHANCED EMISSION; PHOTOLUMINESCENCE MECHANISM; YIELD;
D O I
10.1016/j.dyepig.2019.108106
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A novel concept of anti-counterfeiting is proposed, based on the special properties of excitation-dependent-fluorescence (EDF) and emission-dependent-excitation (EDE) of carbon dots (CDs) in polymer matrix. EDF and EDE behaviors can be controlled by adjusting the concentration of CDs or changing species of CDs and their corresponding polymer matrix. Meanwhile, multi-emission in EDF spectrum is observed, which is helpful to identification. Particularly, the curves in EDF or EDE spectrum as unique and sophisticated as human fingerprints are highly difficult to replicate, which promise practical applications of CDs in the field of anti-counterfeiting.
引用
收藏
页数:10
相关论文
共 30 条
[1]   A New Anti-Counterfeiting Feature Relying on Invisible Luminescent Full Color Images Printed with Lanthanide-Based Inks [J].
Andres, Julien ;
Hersch, Roger D. ;
Moser, Jacques-Edouard ;
Chauvin, Anne-Sophie .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (32) :5029-5036
[2]   Significant Influence of Distance between Amine Groups on Intrinsic Fluorescence Properties [J].
Cao, Lei ;
Jia, Dandan ;
Wang, Shaofei ;
Rong, Yunlong ;
Liu, Chun ;
Wang, Dongjun .
CHEMISTRY LETTERS, 2014, 43 (02) :246-248
[3]   Concentration-induced multi-colored emissions in carbon dots: origination from triple fluorescent centers [J].
Chen, Yeqing ;
Lian, Hongzhou ;
Wei, Yi ;
He, Xin ;
Chen, Yan ;
Wang, Bo ;
Zeng, Qingguang ;
Lin, Jun .
NANOSCALE, 2018, 10 (14) :6734-6743
[4]   A Self-Quenching-Resistant Carbon-Dot Powder with Tunable Solid-State Fluorescence and Construction of Dual-Fluorescence Morphologies for White Light-Emission [J].
Chen, Yonghao ;
Zheng, Mingtao ;
Xiao, Yong ;
Dong, Hanwu ;
Zhang, Haoran ;
Zhuang, Jianle ;
Hu, Hang ;
Lei, Bingfu ;
Liu, Yingliang .
ADVANCED MATERIALS, 2016, 28 (02) :312-318
[5]   Carbon quantum dots from natural resource: A review [J].
Das, Rashmita ;
Bandyopadhyay, Rajib ;
Pramanik, Panchanan .
MATERIALS TODAY CHEMISTRY, 2018, 8 :96-109
[6]   Highly Efficient Red-Emitting Carbon Dots with Gram-Scale Yield for Bioimaging [J].
Ding, Hui ;
Wei, Ji-Shi ;
Zhong, Ning ;
Gao, Qing-Yu ;
Xiong, Huan-Ming .
LANGMUIR, 2017, 33 (44) :12635-12642
[7]   Magnetically responsive photonic watermarks on banknotes [J].
Hu, Haibo ;
Zhong, Hao ;
Chen, Changle ;
Chen, Qianwang .
JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (19) :3695-3702
[8]   Photonic anti-counterfeiting using structural colors derived from magnetic-responsive photonic crystals with double photonic bandgap heterostructures [J].
Hu, Haibo ;
Chen, Qian-Wang ;
Tang, Jian ;
Hu, Xian-Yi ;
Zhou, Xu-Hui .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (22) :11048-11053
[9]   Uncovering a broad class of fluorescent amine-containing compounds by heat treatment [J].
Jia, Dandan ;
Cao, Lei ;
Wang, Dongni ;
Guo, Xuemin ;
Liang, He ;
Zhao, Fangfang ;
Gu, Yaohang ;
Wang, Dongjun .
CHEMICAL COMMUNICATIONS, 2014, 50 (78) :11488-11491
[10]   Triple-Mode Emission of Carbon Dots: Applications for Advanced Anti-Counterfeiting [J].
Jiang, Kai ;
Zhang, Ling ;
Lu, Junfeng ;
Xu, Chunxiang ;
Cai, Congzhong ;
Lin, Hengwei .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (25) :7231-7235