The first class of square-planar platinum(II) complexes containing electron-poor alkenes. Rare insertion of an alkene into a Pt-alkyl bond

被引：46

作者：

Ganis, P ^{[1
]}

Orabona, I ^{[1
]}

Ruffo, F ^{[1
]}

Vitagliano, A ^{[1
]}

机构：

[1] Univ Naples Federico II, Dipartimento Chim, I-80134 Naples, Italy

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 12期

关键词：

D O I：

10.1021/om9800750

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first class of square-planar Pt(II) complexes bearing electron-poor alkenes, i,e., [PtMe(N,N-chelate)(eta(2)-CH2=CHCOR)]BF4 (R = H, NMe2, Me, OMe), is described. By using N,N ligands with suitable steric properties, it was possible to inhibit olefin dynamic processes in solution, thus allowing a thorough characterization of the complexes. Insertion of methyl acrylate into the Pt-Me bond provides a rare example of migratory insertion of an alkene into a Pt-alkyl bond.

引用

页码：2646 / 2650

页数：5

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