Ionic liquids and their solid-state analogues as materials for energy generation and storage

被引:546
作者
MacFarlane, Douglas R. [1 ]
Forsyth, Maria [2 ]
Howlett, Patrick C. [2 ]
Kar, Mega [1 ]
Passerini, Stefano [3 ,4 ]
Pringle, Jennifer M. [2 ]
Ohno, Hiroyuki [5 ]
Watanabe, Masayoshi [6 ]
Yan, Feng [7 ]
Zheng, Wenjun [8 ]
Zhang, Shiguo [6 ]
Zhang, Jie [1 ]
机构
[1] Monash Univ, Sch Chem, ARC Ctr Excellence Electromat Sci, Clayton, Vic 3800, Australia
[2] Deakin Univ, Inst Frontier Mat, ARC Ctr Excellence Electromat Sci, Burwood, Vic 3125, Australia
[3] Helmholtz Inst Ulm, Helmholtzstr 11, D-89081 Ulm, Germany
[4] Karlsruhe Inst Technol, POB 3640, D-76021 Karlsruhe, Germany
[5] Tokyo Univ Agr & Technol, Grad Sch Engn, FILL, 2-24-16 Nakacho, Koganei, Tokyo, Japan
[6] Yokohama Natl Univ, Dept Chem & Biotechnol, Hodogaya Ku, 79-5 Tokiwadai, Yokohama, Kanagawa 2408501, Japan
[7] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Dept Polymer Sci & Engn, Suzhou 215123, Peoples R China
[8] Nankai Univ, Dept Mat Chem, Tianjin 300071, Peoples R China
关键词
SENSITIZED SOLAR-CELLS; NITROGEN-DOPED CARBON; N-METHYLPYRROLIDINIUM BIS(FLUOROSULFONYL)IMIDE; OF-THE-ART; ELECTROCHEMICAL PROPERTIES; PHYSICOCHEMICAL PROPERTIES; IONOTHERMAL SYNTHESIS; OXYGEN REDUCTION; WATER-MOLECULES; RECENT PROGRESS;
D O I
10.1038/natrevmats.2015.5
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Salts that are liquid at room temperature, now commonly called ionic liquids, have been known for more than 100 years; however, their unique properties have only come to light in the past two decades. In this Review, we examine recent work in which the properties of ionic liquids have enabled important advances to be made in sustainable energy generation and storage. We discuss the use of ionic liquids as media for synthesis of electromaterials, for example, in the preparation of doped carbons, conducting polymers and intercalation electrode materials. Focusing on their intrinsic ionic conductivity, we examine recent reports of ionic liquids used as electrolytes in emerging high-energy-density and low-cost batteries, including Li-ion, Li-O-2, Li-S, Na-ion and Al-ion batteries. Similar developments in electrolyte applications in dye-sensitized solar cells, thermo-electrochemical cells, double-layer capacitors and CO2 reduction are also discussed.
引用
收藏
页数:15
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