Chemicals from Lignin: A Review of Catalytic Conversion Involving Hydrogen

被引：162

作者：

Jing, Yaxuan ^{[1
]}

Dong, Lin ^{[1
]}

Guo, Yong ^{[1
]}

Liu, Xiaohui ^{[1
]}

Wang, Yanqin ^{[1
]}

机构：

[1] East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai Key Lab Funct Mat Chem & Res, Res Inst Ind Catalysis, 130 Meilong Rd, Shanghai 200237, Peoples R China

来源：

CHEMSUSCHEM | 2020年 / 13卷 / 17期

关键词：

aromatics; biomass; heterogeneous catalysis; hydrodeoxygenation; lignin; VAPOR-PHASE HYDRODEOXYGENATION; C-O BONDS; SELECTIVE HYDRODEOXYGENATION; MODEL COMPOUNDS; M-CRESOL; BIO-OIL; AROMATIC-HYDROCARBONS; LIGNOCELLULOSE FRACTIONATION; OXIDATIVE CLEAVAGE; FAST PYROLYSIS;

D O I：

10.1002/cssc.201903174

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lignin is the most abundant biopolymer with aromatic building blocks and its valorization to sustainable chemicals and fuels has extremely great potential to reduce the excessive dependence on fossil resources, although such conversions remain challenging. The purpose of this Review is to present an insight into the catalytic conversion of lignin involving hydrogen, including reductive depolymerization and the hydrodeoxygenation of lignin-derived monomers to arenes, cycloalkanes and phenols, with a main focus on the catalyst systems and reaction mechanisms. The roles of hydrogenation sites (Ru, Pt, Pd, Rh) and acid sites (Nb, Ti, Mo), as well as their interaction in selective hydrodeoxygenation reactions are emphasized. Furthermore, some inspirational strategies for the production of other value-added chemicals are mentioned. Finally, some personal perspectives are provided to highlight the opportunities within this attractive field.

引用

页码：4181 / 4198

页数：18

共 219 条

[51] Synthesis of 1,6-Hexanediol from Cellulose Derived Tetrahydrofuran-Dimethanol with Pt-WOx/TiO2 Catalysts [J].

He, Jiayue ;

Burt, Samuel P. ;

Ball, Madelyn ;

Zhao, Dongting ;

Hermans, Ive ;

Dumesic, James A. ;

Huber, George W. .

ACS CATALYSIS, 2018, 8 (02) :1427-1439

[52] Ni-Catalyzed Cleavage of Aryl Ethers in the Aqueous Phase [J].

He, Jiayue ;

Zhao, Chen ;

Lercher, Johannes A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (51) :20768-20775

[53] Catalytic hydrodeoxygenation of guaiacol over platinum supported on metal oxides and zeolites [J].

Hellinger, Melanie ;

Carvalho, Hudson W. P. ;

Baier, Sina ;

Wang, Di ;

Kleist, Wolfgang ;

Grunwaldt, Jan-Dierk .

APPLIED CATALYSIS A-GENERAL, 2015, 490 :181-192

[54] Phenol Deoxygenation Mechanisms on Fe(110) and Pd(111) [J].

Hensley, Alyssa J. R. ;

Wang, Yong ;

McEwen, Jean-Sabin .

ACS CATALYSIS, 2015, 5 (02) :523-536

[55] Catalyst Support and Solvent Effects during Lignin Depolymerization and Hydrodeoxygenation [J].

Heroguel, Florent ;

Xuan Trung Nguyen ;

Luterbacher, Jeremy S. .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (20) :16952-16958

[56] Selective Production of Biobased Phenol from Lignocellulose-Derived Alkylmethoxyphenols [J].

Huang, Xiaoming ;

Ludenhoff, Jasper M. ;

Dirks, Mike ;

Ouyang, Xianhong ;

Boot, Michael D. ;

Hensen, Emiel J. M. .

ACS CATALYSIS, 2018, 8 (12) :11184-11190

[57] Effective Release of Lignin Fragments from Lignocellulose by Lewis Acid Metal Triflates in the Lignin-First Approach [J].

Huang, Xiaoming ;

Zhu, Jiadong ;

Koranyi, Tams I. ;

Boot, Michael D. ;

Hensen, Emiel J. M. .

CHEMSUSCHEM, 2016, 9 (23) :3262-3267

[58]

Huang XM, 2017, GREEN CHEM, V19, P175, DOI [10.1039/C6GC02962K, 10.1039/c6gc02962k]

[59] Selective hydrogenolysis of phenols and phenyl ethers to arenes through direct C-O cleavage over ruthenium-tungsten bifunctional catalysts [J].

Huang, Yao-Bing ;

Yan, Long ;

Chen, Meng-Yuan ;

Guo, Qing-Xiang ;

Fu, Yao .

GREEN CHEMISTRY, 2015, 17 (05) :3010-3017

[60] Nickel-Tungsten Carbide Catalysts for the Production of 2,5-Dimethylfuran from Biomass- Derived Molecules [J].

Huang, Yao-Bing ;

Chen, Meng-Yuan ;

Yan, Long ;

Guo, Qing-Xiang ;

Fu, Yao .

CHEMSUSCHEM, 2014, 7 (04) :1068-1072

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