Measurements and Modeling of Physicochemical Properties of Pure and Binary Mixtures Containing 1,2-Dimethoxyethane and Some Alcohols

被引：12

作者：

Benkelfat-Seladji, Nihelle Lamia ^{[1
]}

Ouaar, Faiza ^{[1
]}

Hernandez, Ariel ^{[2
]}

Munoz-Rujas, Natalia ^{[3
]}

Bahadur, Indra ^{[4
]}

Ahmed, Nouria Chiali-Baba ^{[1
]}

Montero, Eduardo ^{[3
]}

Negadi, Latifa ^{[1
,5
]}

机构：

[1] Univ Tlemcen, Lab Thermodynam Appl & Modelisat Mol, LATA2M, Tilimsen 13000, Algeria

[2] Univ Catolica Santisima Concepcion, Fac Ingn, Dept Ingn Ind, Concepcion 2850, Chile

[3] Univ Burgos, Escuela Politecn Super, Dept Ingn Electromecan, Burgos 09006, Spain

[4] North West Univ, Fac Nat & Agr Sci, Dept Chem, Mafikeng Campus, ZA-2735 Mmabatho, South Africa

[5] Univ KwaZulu Natal, Thermodynam Res Unit, Sch Engn, ZA-4041 Durban, South Africa

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2021年 / 66卷 / 09期

基金：

新加坡国家研究基金会;

关键词：

EXCESS MOLAR VOLUMES; VAPOR-LIQUID-EQUILIBRIA; EQUATION-OF-STATE; REFRACTIVE-INDEX; ETHYLENE-GLYCOL; ISENTROPIC COMPRESSIBILITIES; SURFACE TENSIONS; 298.15; K; PLUS 1,2-DIMETHOXYETHANE; MOLECULAR-INTERACTIONS;

D O I：

10.1021/acs.jced.1c00131

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In this paper, experimental values of densities, speeds of sound, and refractive indices in a temperature range of 293.15-323.15 K have been measured as a function of composition for the binary liquid mixtures of 1,2-dimethoxyethane with alcohols such as methanol, propan-1-ol, propan-2-ol, and butan-2-ol. From these experimental values, excess/derived properties such as excess molar volume, isentropic compressibility, deviation in isentropic compressibility, and deviation in the refractive index have been calculated. Excess/derived properties have been correlated using the Redlich-Kister equation and physicochemical properties modeled using the cubic plus association equation of state for pure and binary mixtures. The results are interpreted with respect to possible molecular interactions between components.

引用

页码：3397 / 3416

页数：20

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