Directed ortho insertion (DoI): A new approach to functionalized aryl and heteroaryl zinc reagents

被引：79

作者：

Boudet, Nadege ^{[1
]}

Sase, Shohei ^{[1
]}

Sinha, Pradipta ^{[1
]}

Liu, Ching-Yuan ^{[1
]}

Krasovskiy, Arkady ^{[1
]}

Knochel, Paul ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 41期

关键词：

D O I：

10.1021/ja074060h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A wide range of directing groups (ester, ketone, acetate, aryl sulfonate, triazene, carbamate) allow the regioselective directed ortho insertion (DoI) of zinc in the presence of LiCl leading to polyfunctional aryl and heteroaryl zinc reagents.

引用

页码：12358 / +

页数：3

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