Inexpensive polyphenylene network polymers with enhanced microporosity

被引：78
作者：
Msayib, Kadhum J. [1 ]
McKeown, Neil B. [1 ]
机构：
[1] Univ Edinburgh, EastChem Sch Chem, David Brewster Rd, Edinburgh EH9 3JF, Midlothian, Scotland
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 26期
基金：
英国工程与自然科学研究理事会;
关键词：
COVALENT-ORGANIC POLYMERS; POROUS AROMATIC FRAMEWORKS; SOLVENT-FREE CONDITIONS; CARBON-DIOXIDE CAPTURE; HIGH-SURFACE-AREA; INTRINSIC MICROPOROSITY; GAS-STORAGE; HETEROGENEOUS CATALYSIS; ADSORPTION PROPERTIES; EFFICIENT SYNTHESIS;
D O I：
10.1039/c6ta03257e
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Greatly enhanced microporosity is obtained for the amorphous porous polymers produced from the AlCl3-mediated coupling of aromatic hydrocarbons by using dichloromethane as the reaction solvent. A polymer of average BET surface area = 2435 m(2) g(-1) was obtained reproducibly from 1,3,5-triphenylbenzene with the additional porosity being provided as ultramicroporosity as demonstrated by very high CO2 adsorption at 273 K/1 bar.
引用
收藏
页码：10110 / 10113
页数：4
相关论文
共 46 条
[1]   Rapid generation and control of microporosity, bimodal pore size distribution, and surface area in Davankov-type hyper-cross-linked resins [J].
Ahn, JH ;
Jang, JE ;
Oh, CG ;
Ihm, SK ;
Cortez, J ;
Sherrington, DC .
MACROMOLECULES, 2006, 39 (02) :627-632
[2]   Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area [J].
Ben, Teng ;
Ren, Hao ;
Ma, Shengqian ;
Cao, Dapeng ;
Lan, Jianhui ;
Jing, Xiaofei ;
Wang, Wenchuan ;
Xu, Jun ;
Deng, Feng ;
Simmons, Jason M. ;
Qiu, Shilun ;
Zhu, Guangshan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) :9457-9460
[3]   Triptycene Induced Enhancement of Membrane Gas Selectivity for Microporous Troger's Base Polymers [J].
Carta, Mariolino ;
Croad, Matthew ;
Malpass-Evans, Richard ;
Jansen, Johannes C. ;
Bernardo, Paola ;
Clarizia, Gabriele ;
Friess, Karel ;
Lanc, Marek ;
McKeown, Neil B. .
ADVANCED MATERIALS, 2014, 26 (21) :3526-3531
[4]   Microporous organic polymers for gas storage and separation applications [J].
Chang, Ze ;
Zhang, Da-Shuai ;
Chen, Qiang ;
Bu, Xian-He .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (15) :5430-5442
[5]   Nanoporous organic polymer networks [J].
Dawson, Robert ;
Cooper, Andrew I. ;
Adams, Dave J. .
PROGRESS IN POLYMER SCIENCE, 2012, 37 (04) :530-563
[6]   Microporous organic polymers for carbon dioxide capture [J].
Dawson, Robert ;
Stoeckel, Ev ;
Holst, James R. ;
Adams, Dave J. ;
Cooper, Andrew I. .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (10) :4239-4245
[7]   High Surface Area Conjugated Microporous Polymers: The Importance of Reaction Solvent Choice [J].
Dawson, Robert ;
Laybourn, Andrea ;
Khimyak, Yaroslav Z. ;
Adams, Dave J. ;
Cooper, Andrew I. .
MACROMOLECULES, 2010, 43 (20) :8524-8530
[8]   Hypercrosslinked materials: preparation, characterisation and applications [J].
Fontanals, N. ;
Marce, R. M. ;
Borrull, F. ;
Cormack, P. A. G. .
POLYMER CHEMISTRY, 2015, 6 (41) :7231-7244
[9]   Triptycene-Based Polymers of Intrinsic Microporosity: Organic Materials That Can Be Tailored for Gas Adsorption [J].
Ghanem, Bader S. ;
Hashem, Mohammed ;
Harris, Kenneth D. M. ;
Msayib, Kadhum J. ;
Xu, Mingcan ;
Budd, Peter M. ;
Chaukura, Nhamo ;
Book, David ;
Tedds, Steven ;
Walton, Allan ;
McKeown, Neil B. .
MACROMOLECULES, 2010, 43 (12) :5287-5294
[10]   Comparison of Oxidative Aromatic Coupling and the Scholl Reaction [J].
Grzybowski, Marek ;
Skonieczny, Kamil ;
Butenschoen, Holger ;
Gryko, Daniel T. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (38) :9900-9930
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