Versatility of the nature of the magnetic gadolinium(III)-vanadium(IV) interaction - Structure and magnetic properties of two heterobinuclear [Gd, V(O)] complexes

被引：0

作者：

Costes, JP

Dahan, F

Donnadieu, B

Garcia-Tojal, J

Laurent, JP

机构：

[1] Univ Toulouse 3, UPR 8241, CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

[2] Inst Natl Polytech Toulouse, F-31077 Toulouse, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2001年 / 02期

关键词：

Schiff bases; vanadium; lanthanides; magnetic properties;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

It has been known for a long time that the magnetic exchange interaction between copper and gadolinium ions is always ferromagnetic. Very recently, three exceptions to this general trend were revealed. They involve complexes associating a gadolinium(III) ion with a copper(II) ion or with radicals of the nitroxide or semiquinone types. We want to show that this trend is more general than expected, for such a behavior can also be observed in heterobinuclear vanadyl-gadolinium complexes.

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页码：363 / 365

页数：3

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