The tetragonal layered compounds TbTiGe and ErTiGe order antiferromagnetically at 276K and 39 K, respectively. Partial substitution of Mo for Ti in these two compounds modifies the magnetic interactions giving rise to a ferromagnetic ground state which results in an enhanced magnetocaloric effect. The magnetic entropy change in ErTi0.85Mo0.15Ge for a magnetic field change of 5T is similar to 10.5J/kg/K as against similar to 0.8J/ kg/ K for ErTiGe in the vicinity of the magnetic transition. Thus, magnetocaloric properties of such layered materials may be tunable by suitable chemical substitutions. Copyright (C) EPLA, 2007.