3d Metal Ions in Highly Unusual Eight-Coordination: The Phosphate-Capped Dodecapalladate(II) Nanocube

被引：34
作者：
Barsukova-Stuckart, Maria [3 ]
Izarova, Natalya V. [3 ,6 ]
Barrett, Ryan [1 ,2 ]
Wang, Zhenxing [1 ,2 ]
van Tol, Johan [1 ,2 ]
Kroto, Harold W. [1 ,2 ]
Dalal, Naresh S. [1 ,2 ]
Keita, Bineta [4 ]
Heller, Detlef [5 ]
Kortz, Ulrich [3 ]
机构：
[1] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA
[2] Florida State Univ, NHMFL, Tallahassee, FL 32306 USA
[3] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany
[4] Univ Paris 11, Lab Chim Phys, UMR 8000, CNRS,Equipe Electrochim & Photoelectrochim, F-91405 Orsay, France
[5] Leibniz Inst Catalysis LIKAT, D-18059 Rostock, Germany
[6] Nikolaev Inst Inorgan Chem SB RAS, Novosibirsk 630090, Russia
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 20期
关键词：
magnetic properties; palladium; polyoxometalates; structure elucidation; transition metals; TRANSITION-METAL; COMPLEXES; CRYSTAL; PALLADIUM; CLUSTER;
D O I：
10.1002/chem.201200060
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Trapped in a noble cube: A novel family of noble metalates has been discovered in which a 3d metal ion M (M=Mn II, Fe III, Co II, Cu II, Zn II) is encapsulated by a 12 palladium-oxo cage {Pd 12O 32}, which is capped by eight phosphate groups. Such discrete nanocubes were further investigated by EPR spectroscopy, electrochemistry, and in homogeneous hydrogenation catalysis. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：6167 / 6171
页数：5
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