Synthesis of N,N′-diferrocenylmethyl-(1S,2S)-1,2-diphenylethanediamine and its application as chiral ligand to the asymmetric dihydroxylation of olefins

被引：0

作者：

Li, XS ^{[1
]}

Ge, JF

Kong, LC

机构：

[1] Zhejiang Normal Univ, Dept Biol & Chem, Jinhua 321004, Peoples R China

[2] Suzhou Univ, Dept Mat & Engn, Suzhou 215006, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 25卷 / 11期

关键词：

N,N '-diferrocenylmethyl-(lS,2S)-1,2-diphenylethanediamine; asymmetric dihydroxylation; chiral vicinal diol;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N,N'-Diferrocenylmethyl-(1S,2S)-1,2-diphenylethanediamine was synthesized by two steps from (1S,2S)-1,2-diphenylethanedianiine and ferrocenealdehyde, and has been used as chiral ligand to asymmetric dihydroxylation of olefins. A good enantioselectivity (71%similar to 86% ee) has been achieved.

引用

页码：1487 / 1489

页数：3

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