Lateral potential energy surfaces for molecular chemisorption on metals from experiment and theory: NO on Pt{110}-(1x2)

被引：23

作者：

Brown, WA ^{[1
]}

Ge, Q ^{[1
]}

Sharma, RK ^{[1
]}

King, DA ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 299卷 / 3-4期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0009-2614(98)01272-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The suppression of diffusion of chemisorbed species at very low temperatures is exploited, using infrared spectroscopy, to determine local minima and diffusion barriers in the lateral potential energy surface for adsorption. These are compared with results from density functional theory slab calculations. This methodology provides the first detailed lateral potential energy surface for the chemisorption of NO, on Pt{110}-(1 x 2). (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：253 / 259

页数：7

共 50 条

[21] MICROCALORIMETRIC STUDY OF ETHYLENE ON PT(110)-(1X2)
STUCK, A
WARTNABY, CE
YEO, YY
KING, DA
PHYSICAL REVIEW LETTERS, 1995, 74 (04) : 578 - 581
[22] Adsorption dynamics of water on Pt{110}-(1x2)
Laffir, Fathima R.
Fiorin, Vittorio
King, David A.
JOURNAL OF CHEMICAL PHYSICS, 2008, 128 (11):
[23] WATER-ADSORPTION ON PT(110) (1X2)
FUSY, J
DUCROS, R
SURFACE SCIENCE, 1990, 237 (1-3) : 53 - 62
[24] ALKANE DISSOCIATION DYNAMICS ON PT(110)-(1X2)
MCMASTER, MC
MADIX, RJ
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (12): : 9963 - 9976
[25] Dynamics of dissociative methane adsorption on metals:: CH4 on Pt{110}(1x2)
Walker, AV
King, DA
JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (10): : 4739 - 4748
[26] IR EVIDENCE FOR THE MOLECULAR-REORIENTATION OF LINEAR CO ON PT(110)-(1X2)
HAYDEN, BE
ROBINSON, AW
TUCKER, PM
SURFACE SCIENCE, 1987, 192 (01) : 163 - 171
[27] STUDY OF COBALT FILMS DEPOSITED ON PT(110)(1X2)
ALNOT, M
FUSY, J
APPLIED SURFACE SCIENCE, 1992, 55 (2-3) : 209 - 219
[28] Surface microstructure effects: Molecular ethane adsorption dynamics on Pt(110)-(1x2)
Stinnett, JA
McMaster, MC
Schroeder, SLM
Madix, RJ
SURFACE SCIENCE, 1996, 365 (03) : 683 - 700
[29] SPATIAL-DISTRIBUTION OF REACTIVE CO2 DESORPTION ON PT(110)(1X2) SURFACES
MATSUSHIMA, T
SURFACE SCIENCE, 1991, 242 (1-3) : 489 - 492
[30] Multilayer influences on the monolayer structure for NO on Pt{110}-(1x2)
Brown, WA
Sharma, RK
Ge, QF
King, DA
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (08) : 1995 - 2000

← 1 2 3 4 5 →