Self-Assembly of Pt(II) Spherical Complexes via Temporary Labilization of the Metal-Ligand Association in 2,2,2-Trifluoroethanol

被引：96
作者：
Fujita, Daishi
Takahashi, Asana
Sato, Sota
Fujita, Makoto [1 ]
机构：
[1] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 34期
关键词：
IONIZATION MASS-SPECTROMETRY; COMPONENTS;
D O I：
10.1021/ja2059236
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Thermodynamically controlled platinum(II) spherical complexes were synthesized via temporary labilization of inert Pt(II)-pyridine bonds by the addition of the strong hydrogen-bond donor 2,2,2-trifluoroethanol (TFE), which weakens the pyridine metal interaction. The platinum complex was stably trapped after removal of TFE and showed higher acid durability than its palladium counterpart.
引用
收藏
页码：13317 / 13319
页数：3
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