Spatial structure of triglycine determined by the residual dipolar coupling analysis

被引:13
|
作者
Klochkov, VV [1 ]
Khairutdinov, BI [1 ]
Klochkov, AV [1 ]
Shtyrlin, VG [1 ]
Shaykhutdinov, RA [1 ]
机构
[1] Kazan VI Lenin State Univ, Dept Chem, Kazan 420008, Russia
关键词
D O I
10.1007/BF03166971
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The possibility to determine the relatively small organic compound conformations by the approach on the basis of the analysis of the residual dipolar couplings H-1-C-13 in the molecules partially aligned in lyotropic liquid crystalline media has been considered. This approach has been used in the nuclear magnetic resonance investigation of the triglycine structure in lyotropic medium (cetylpyridinium bromide/n-hexanol). The conformation of triglycine in solution has been established as transtrans on the basis of the experimental data of observed couplings.
引用
收藏
页码:113 / 119
页数:7
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