Continuous synthesis of aligned carbon nanotube arrays on copper substrates using laser-activated gas jet

被引:3
作者
Arkhipov, V. E. [1 ]
Smirnov, A. L. [2 ]
Grachev, G. N. [2 ]
Bagayev, S. N. [2 ]
Gusel'nikov, A. V. [1 ]
Bulusheva, L. G. [1 ,3 ]
Okotrub, A. V. [1 ,3 ]
机构
[1] RAS, Nikolaev Inst Inorgan Chem SB, 3 Akad Lavrentiev Ave, Novosibirsk 630090, Russia
[2] RAS, Inst Laser Phys SB, 13-3 Akad Lavrentiev Ave, Novosibirsk 630090, Russia
[3] Tomsk State Univ, 36 Lenin Ave, Tomsk 634050, Russia
关键词
CHEMICAL-VAPOR-DEPOSITION; FIELD-EMISSION PROPERTIES; GROWTH; AEROSOL; TEMPERATURE; NUCLEATION; II;
D O I
10.1063/1.5052283
中图分类号
O59 [应用物理学];
学科分类号
摘要
A method has been developed for continuous synthesis of carbon nanotube (CNT) arrays on large-area metal substrates using a reactor that moves above the substrate surface with a given scan rate. The reagent vapors pass through the region of plasma laser discharge towards the substrate surface screened by an argon flow from the external atmosphere. Vertically aligned multiwalled CNTs (MWCNTs) are formed on copper as a result of decomposition of ethylene and the vapor of iron pentacarbonyl. The main parameters of laser plasma discharge, gas jets, and concentrations of feed compounds have been estimated in terms of their effect on the growth rate and MWCNT morphology. The measurements of MWCNTs/Cu field emission characteristics have been used to determine optimal synthesis parameters for the fabrication of effective field emission cathodes. Published by AIP Publishing.
引用
收藏
页数:5
相关论文
共 44 条
[1]   A new method of laser-plasma synthesis of nanomaterials: First results and prospects [J].
Bagayev, S. N. ;
Grachev, G. N. ;
Ponomarenko, A. G. ;
Smirnov, A. L. ;
Demin, V. N. ;
Okotrub, A. V. ;
Baklanov, A. M. ;
Onischuk, A. A. .
INTERNATIONAL CONFERENCE ON LASERS, APPLICATIONS, AND TECHNOLOGIES 2007: LASER-ASSISTED MICRO- AND NANOTECHNOLOGIES, 2007, 6732
[2]   Nucleation and growth of carbon nanotubes by microwave plasma chemical vapor deposition [J].
Bower, C ;
Zhou, O ;
Zhu, W ;
Werder, DJ ;
Jin, SH .
APPLIED PHYSICS LETTERS, 2000, 77 (17) :2767-2769
[3]   HOMOGENEOUS NUCLEATION OF DIAMOND POWDER BY CO2-LASER-DRIVEN GAS-PHASE REACTIONS [J].
BUERKI, PR ;
LEUTWYLER, S .
JOURNAL OF APPLIED PHYSICS, 1991, 69 (06) :3739-3744
[4]   ELECTRON FIELD-EMISSION FROM NANOFILAMENT CARBON-FILMS [J].
CHERNOZATONSKII, LA ;
GULYAEV, YV ;
KOSAKOVSKAJA, ZJ ;
SINITSYN, NI ;
TORGASHOV, GV ;
ZAKHARCHENKO, YF ;
FEDOROV, EA ;
VALCHUK, VP .
CHEMICAL PHYSICS LETTERS, 1995, 233 (1-2) :63-68
[5]   A CARBON NANOTUBE FIELD-EMISSION ELECTRON SOURCE [J].
DEHEER, WA ;
CHATELAIN, A ;
UGARTE, D .
SCIENCE, 1995, 270 (5239) :1179-1180
[6]   One-step growth of graphene-carbon nanotube hybrid materials by chemical vapor deposition [J].
Dong, Xiaochen ;
Li, Bing ;
Wei, Ang ;
Cao, Xiehong ;
Chan-Park, M. B. ;
Zhang, Hua ;
Li, Lain-Jong ;
Huang, Wei ;
Chen, Peng .
CARBON, 2011, 49 (09) :2944-2949
[7]   Self-oriented regular arrays of carbon nanotubes and their field emission properties [J].
Fan, SS ;
Chapline, MG ;
Franklin, NR ;
Tombler, TW ;
Cassell, AM ;
Dai, HJ .
SCIENCE, 1999, 283 (5401) :512-514
[8]   Supercapacitor performance of vertically aligned multiwall carbon nanotubes produced by aerosol-assisted CCVD method [J].
Fedorovskaya, E. O. ;
Bulusheva, L. G. ;
Kurenya, A. G. ;
Asanov, I. P. ;
Rudina, N. A. ;
Funtov, K. O. ;
Lyubutin, I. S. ;
Okotrub, A. V. .
ELECTROCHIMICA ACTA, 2014, 139 :165-172
[9]   RNA-modified carbon nanotube arrays recognizing RNA via electrochemical capacitance response [J].
Fedorovskaya, Ekaterina O. ;
Apartsin, Evgeny K. ;
Novopashina, Darya S. ;
Venyaminova, Alya G. ;
Kurenya, Alexander G. ;
Bulusheva, Lyubov G. ;
Okotrub, Alexander V. .
MATERIALS & DESIGN, 2016, 100 :67-72
[10]   Effect of substrate temperature on the structure of amorphous oxygenated hydrocarbon films grown with a pulsed supersonic methane plasma flow [J].
Fedoseeva, Yu. V. ;
Pozdnyakov, G. A. ;
Okotrub, A. V. ;
Kanygin, M. A. ;
Nastaushev, Yu. V. ;
Vilkov, O. Y. ;
Bulusheva, L. G. .
APPLIED SURFACE SCIENCE, 2016, 385 :464-471