Stepwise deposition of metal organic frameworks on flexible synthetic polymer surfaces

被引：70

作者：

Meilikhov, Mikhail ^{[2
]}

Yusenko, Kirill ^{[2
]}

Schollmeyer, Eckhardt ^{[1
]}

Mayer, Christian ^{[3
]}

Buschmann, Hans-Juergen ^{[1
]}

Fischer, Roland A. ^{[2
]}

机构：

[1] Deutsch Text Forschungszentrum Nord W eV, D-47798 Krefeld, Germany

[2] Ruhr Univ Bochum, Dept Inorgan Chem 2, D-44780 Bochum, Germany

[3] CeNIDE Univ Duisburg Essen, Inst Phys Chem, D-45117 Essen, Germany

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 18期

关键词：

D O I：

10.1039/c0dt01820a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thin films of [Cu(3)(btc)(2)](n) (btc=1,3,5-benzenetricarboxylate)metal organic framework were deposited in a stepwise manner on surfaces of flexible organic polymers. The thickness of films can be precisely controlled. The deposition of the first cycles was monitored by UV-vis spectroscopy. The porosity was proven by the adsorption of pyrazine, which was monitored by FT-IR and thermogravimetric analysis. The deposition of MOF thin films on flexible polymer surfaces might be a new path for the fabrication of functional materials for different applications, such as protection layers for working clothes and gas separation materials in the textile industry.

引用

页码：4838 / 4841

页数：4

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