Low-voltage carbon films deposition by electro-exfoliation of graphite into graphene oxide

被引:4
作者
Sakita, Alan M. P. [1 ]
Valente, Marco A. G., Jr. [1 ]
Della Noce, Rodrigo [2 ]
Fugivara, Cecilio S. [1 ]
Magnani, Marina [1 ]
Benedetti, Assis V. [1 ]
机构
[1] UNESP Univ Estadual Paulista, Inst Quim, BR-14800900 Araraquara, Brazil
[2] Inst Super Tecn, Dept Chem Engn, Ctr Quim Estrut CQE, Lisbon, Portugal
关键词
DIAMOND-LIKE CARBON; DLC FILMS; TRIBOLOGICAL PROPERTIES; ELECTRODEPOSITION; REDUCTION; MECHANISM; EVOLUTION; DISCHARGE; COATINGS; SILICA;
D O I
10.1039/c6ra16502h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Low-voltage carbon films deposition by electro-exfoliation of graphite into graphene oxide is reported. By simply employing two different anodes, Pt or graphite, it is demonstrated that the carbon film deposition takes place by the graphite electro-exfoliation and not by the carbonic molecules from the electrolyte as has been frequently reported. By means of Raman spectroscopy, scanning electron microscopy (SEM), cyclic voltammetry (CV), X-ray diffractometry (XRD), atomic force microscopy (AFM), and dynamic light scattering (DLS), graphene oxide is successfully characterized. In addition, this electro-exfoliation process may be an alternative green route for the production of graphene oxide.
引用
收藏
页码:84194 / 84199
页数:6
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