Characterization of reaction intermediates by ion spectroscopy

被引：160
|
作者：
Roithova, Jana [1 ]
机构：
[1] Charles Univ Prague, Fac Sci, Dept Organ & Nucl Chem, Prague 12843 2, Czech Republic
来源：
CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 02期
基金：
欧洲研究理事会;
关键词：
ELECTROSPRAY-IONIZATION MASS; CROSS-COUPLING REACTIONS; BAYLIS-HILLMAN REACTION; GAS-PHASE OXIDATION; INFRARED-SPECTROSCOPY; VIBRATIONAL SPECTROSCOPY; METAL-IONS; COMPLEXES; SPECTROMETRY; METHANOL;
D O I：
10.1039/c1cs15133a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the last decade, we have experienced massive progress in spectroscopic methods for mass-selected ions. The aim of this tutorial review is to present action spectroscopy as a powerful tool for the investigation of ionic reaction intermediates. Examples span from ultraviolet and infrared photodissociation spectroscopy of model reaction intermediates to applications of infrared multiphoton dissociation spectroscopy (IRMPD) to intermediates directly sampled from reaction mixtures. The first example of double resonance IR-UV spectroscopy of model intermediates in an organometallic reaction is also mentioned.
引用
收藏
页码：547 / 559
页数：13
相关论文
共 50 条
  • [41] Quantum Chemical Investigation of the Transition States and Intermediates for the Reaction of the Nitrosonium Ion with the Pentaammineazidocobalt(III) Ion
    Rotzinger, Francois P.
    INORGANIC CHEMISTRY, 2016, 55 (24) : 12707 - 12715
  • [42] Elusive intermediates in cisplatin reaction with target amino acids: Platinum(II)-cysteine complexes assayed by IR ion spectroscopy and DFT calculations
    Corinti, Davide
    Paciotti, Roberto
    Coletti, Cecilia
    Re, Nazzareno
    Chiavarino, Barbara
    Crestoni, Maria Elisa
    Fornarini, Simonetta
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2022, 237
  • [43] Absorption spectroscopy in studies of visual pigments: Spectral and kinetic characterization of intermediates
    Lewis, JW
    Kliger, DS
    VERTEBRATE PHOTOTRANSDUCTION AND THE VISUAL CYCLE, PART A, 2000, 315 : 164 - 178
  • [44] In Situ Reaction Monitoring of Unstable Lithiated Intermediates through Inline FTIR Spectroscopy
    Fath, Verena
    Kockmann, Norbert
    Roeder, Thorsten
    CHEMICAL ENGINEERING & TECHNOLOGY, 2019, 42 (10) : 2095 - 2104
  • [45] Unravelling potential reaction intermediates during catalytic pyrolysis of polypropylene with microscopy and spectroscopy
    Vollmer, Ina
    Jenks, Michael J. F.
    Rejman, Sebastian
    Meirer, Florian
    Gurinov, Andrei
    Baldus, Marc
    Weckhuysen, Bert M.
    CATALYSIS SCIENCE & TECHNOLOGY, 2024, 14 (04) : 894 - 902
  • [46] Topaquinone-dependent amine oxidases: Identification of reaction intermediates by Raman spectroscopy
    Nakamura, N
    MoenneLoccoz, P
    Tanizawa, K
    Mure, M
    Suzuki, S
    Klinman, JP
    SandersLoehr, J
    BIOCHEMISTRY, 1997, 36 (38) : 11479 - 11486
  • [47] STUDIES OF ELECTROCHEMICALLY GENERATED REACTION INTERMEDIATES USING MODULATED SPECULAR REFLECTANCE SPECTROSCOPY
    AYLMERKE.AW
    BEWICK, A
    CANTRILL, PR
    TUXFORD, AM
    FARADAY DISCUSSIONS, 1973, 56 : 96 - 107
  • [48] Exchange coupling constant J of peroxodiferric reaction intermediates determined by Mossbauer spectroscopy
    Krebs, C
    Bollinger, JM
    Theil, EC
    Huynh, BH
    JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2002, 7 (7-8): : 863 - 869
  • [49] Reaction intermediates of ethanol electro-oxidation on Platinum investigated by SFG spectroscopy
    Gomes, Janaina F.
    Bergamaski, Kleber
    Pinto, Melissa F. S.
    Miranda, Paulo B.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [50] FLUORESCENCE SPECTROSCOPY OF ORGANIC-REACTION INTERMEDIATES IN SOLUTION USING A COMMERCIAL SPECTROFLUORIMETER
    CASAL, HL
    SCAIANO, JC
    CHARETTE, GM
    SUGAMORI, SE
    REVIEW OF SCIENTIFIC INSTRUMENTS, 1985, 56 (01): : 23 - 25
12345