Characterization of reaction intermediates by ion spectroscopy

被引：160
|
作者：
Roithova, Jana [1 ]
机构：
[1] Charles Univ Prague, Fac Sci, Dept Organ & Nucl Chem, Prague 12843 2, Czech Republic
来源：
CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 02期
基金：
欧洲研究理事会;
关键词：
ELECTROSPRAY-IONIZATION MASS; CROSS-COUPLING REACTIONS; BAYLIS-HILLMAN REACTION; GAS-PHASE OXIDATION; INFRARED-SPECTROSCOPY; VIBRATIONAL SPECTROSCOPY; METAL-IONS; COMPLEXES; SPECTROMETRY; METHANOL;
D O I：
10.1039/c1cs15133a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the last decade, we have experienced massive progress in spectroscopic methods for mass-selected ions. The aim of this tutorial review is to present action spectroscopy as a powerful tool for the investigation of ionic reaction intermediates. Examples span from ultraviolet and infrared photodissociation spectroscopy of model reaction intermediates to applications of infrared multiphoton dissociation spectroscopy (IRMPD) to intermediates directly sampled from reaction mixtures. The first example of double resonance IR-UV spectroscopy of model intermediates in an organometallic reaction is also mentioned.
引用
收藏
页码：547 / 559
页数：13
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