Direct electrochemistry of redox enzymes as a tool for mechanistic studies

被引:630
作者
Leger, Christophe [1 ]
Bertrand, Patrick
机构
[1] IBSM, CNRS, Lab Bioenerget & Ingn Prot, UPR 9036, F-13402 Marseille 20, France
关键词
D O I
10.1021/cr0680742
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A review regarding dynamic electrochemistry on its usage for studying the mechanism of redox enzymes is given as well as the configuration where the protein is adsorbed in an electrode where the electron transfer is direct. In addition, the kinetic and molecular aspects of the catalytic mechanism of redox enzymes will also be discussed as well as the modeling of the voltammetry of adsorbed redox enzymes. The result of the study found out that there is a need for new strategies that will be used for adsorbing the enzymes in innocent electrodes, strategies that will combine spectroscopic techniques and direct and catalytic electrochemistry.
引用
收藏
页码:2379 / 2438
页数:60
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