Catalytic activity of 1-methylimidazole-based phosphine ligands in the palladium-catalyzed Suzuki coupling reaction

被引：13

作者：

Guan, Jin Tao ^{[1
]}

Song, Xiao Ming ^{[1
]}

Zhang, Zhi Yong ^{[1
]}

Wei, Ben Mei ^{[1
]}

Dai, Zhi Qun ^{[1
]}

机构：

[1] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2015年 / 29卷 / 02期

关键词：

1-methylimidazole; phosphine ligand; Suzuki coupling reaction; ARYL CHLORIDES; BIFUNCTIONAL CATALYST; EFFICIENT; ISOMERIZATION; ACTIVATION; BROMIDES; ALKENES; HECK;

D O I：

10.1002/aoc.3249

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The catalytic activities of three N-methylimidazole-based phosphine ligands in the Suzuki coupling reaction were tested using PdCl2 as the catalyst. The results showed all three phosphine ligands exhibited excellent activity towards the Suzuki reaction, and the catalytic activity decreased with increasing number of imidazole groups. Copyright (C) 2014 John Wiley & Sons, Ltd.

引用

页码：87 / 89

页数：3

共 30 条

[1] Green chemistry tools to influence a medicinal chemistry and research chemistry based organisation [J].

Alfonsi, Kim ;

Colberg, Juan ;

Dunn, Peter J. ;

Fevig, Thomas ;

Jennings, Sandra ;

Johnson, Timothy A. ;

Kleine, H. Peter ;

Knight, Craig ;

Nagy, Mark A. ;

Perry, David A. ;

Stefaniak, Mark .

GREEN CHEMISTRY, 2008, 10 (01) :31-36

[2] Oxime-derived palladacycles as source of palladium nanoparticles [J].

Alonso, Diego A. ;

Najera, Carmen .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (08) :2891-2902

[3] Non-conventional methodologies for transition-metal catalysed carbon-carbon coupling: a critical overview. Part 2: The Suzuki reaction [J].

Alonso, Francisco ;

Beletskaya, Irina P. ;

Yus, Miguel .

TETRAHEDRON, 2008, 64 (14) :3047-3101

[4] Catalysts for Suzuki-Miyaura coupling processes: Scope and studies of the effect of ligand structure [J].

Barder, TE ;

Walker, SD ;

Martinelli, JR ;

Buchwald, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (13) :4685-4696

[5]

Brunel JM, 2000, ANGEW CHEM INT EDIT, V39, P1946, DOI 10.1002/1521-3773(20000602)39:11<1946::AID-ANIE1946>3.0.CO

[6]

2-I

[7] Mild and Selective Deuteration and Isomerization of Alkenes by a Bifunctional Catalyst and Deuterium Oxide [J].

Erdogan, Guelin ;

Grotjahn, Douglas B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (30) :10354-+

[8] Sterically demanding trialkylphosphines for palladium-catalyzed cross coupling reactions-alternatives to PtBu3 [J].

Fleckenstein, Christoph A. ;

Plenio, Herbert .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (02) :694-711

[9] When phosphorus and NHC (N-heterocyclic carbene) meet each other [J].

Gaillard, Sylvain ;

Renaud, Jean-Luc .

DALTON TRANSACTIONS, 2013, 42 (20) :7255-7270

[10] Extensive isomerization of alkenes using a bifunctional catalyst: An alkene zipper [J].

Grotjahn, Douglas B. ;

Larsen, Casey R. ;

Gustafson, Jeffery L. ;

Nair, Reji ;

Sharma, Abhinandini .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (31) :9592-+

← 1 2 3 →