Reductive coupling of acetonitrile by uranium and thorium hydride complexes to give cyanopentadienyl dianion (C6N3H7)2-

被引：24

作者：

Evans, William J. ^{[1
]}

Miller, Kevin A. ^{[1
]}

Ziller, Joseph W. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 03期

关键词：

actinides; cyclopentadienyl ligands; hydrides; nitriles; reduction;

D O I：

10.1002/anie.200703969

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The actinide metallocene hydrides [{(C 5Me5)2UH}2] and [{(C 5Me5)2ThH2}2] convert three equivalents of acetonitrile into a polydentate ligand containing a six carbon atom chain (see scheme). These reactions show that a ThIV hydride moiety can undergo chemistry similar to UIII in a multistep reaction. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：589 / 592

页数：4

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