A novel spin transition compound with hysteresis [Fe(PhCH=Ntrz)3](BF4)2•3H2O

被引：0

作者：

Wang, HM

Li, LC

Yang, GM

Liao, DZ ^{[1
]}

Yan, SP

Jiang, ZH

Wang, GL

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Chinese Acad Sci, Inst High Energy Phys, Beijing 100080, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 1998年 / 19卷 / 07期

关键词：

iron(II) complex; spin transition; hysteresis; thermochromism;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spin transition complexes are of great interest because of their potential application in molecular based electronic devices such as optical memory and switches. A novel linear polynuclear spin transition complex [Fe (PhCH = Ntrz)(3)] (BF4)(2). 3H(2)O (where PhCH=Ntrz stood for the Schiff base condensed by 4-NH2-1, 2, 4-triazole and benzaldehyde) was synthesized and characterized by elemental analysis, molar conductance, IR and UV-Vis spectra, magnetic measurements and temperature-dependence optical detection. The spin transition occurred at 105 similar to 235 K with hysteresis and pronounced thermochromism, T-c up arrow =180 K, T-c down arrow =169 K, hysteresis width 11 K.

引用

页码：1020 / 1022

页数：3

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