Sorption of copper onto low molecular weight chitosan derivative from aqueous solution

被引：15

作者：

Boamah, Peter Osei ^{[1
,2
]}

Huang, Yan ^{[1
]}

Hua, Mingqing ^{[1
]}

Onumah, Jacqueline ^{[2
]}

Sam-Amoah, Livingstone K. ^{[4
]}

Boamah, Paul Osei ^{[5
]}

Qian, Yaao ^{[3
]}

Zhang, Qi ^{[1
,3
]}

机构：

[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China

[2] Bolgatanga Polytech, Dept Ecol Agr, Bolgatanga, Ghana

[3] Hainan Univ, Hainan Prov Key Lab Fine Chem, Haikou 570228, Peoples R China

[4] Univ Cape Coast, Sch Agr, Cape Coast, Ghana

[5] MMG, Dept Geol, PMB 7, Geraldton, WA, Australia

来源：

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY | 2016年 / 129卷

基金：

中国国家自然科学基金;

关键词：

Sorption; Copper; Chitosan derivative; Isotherms; Thermodynamics; ADSORPTION PROPERTIES; CU(II) IONS; METAL-IONS; REMOVAL; BEADS; DYE; THERMODYNAMICS; EQUILIBRIUM; BIOSORPTION; COMPOSITE;

D O I：

10.1016/j.ecoenv.2016.01.014

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

In this study, sorption of copper onto low molecular weight chitosan derivative was studied. Experimental parameters such as pH of the solution (A), temperature (B), dose of the sorbent (C), and concentration of solution (D) were considered. The statistical results indicated that the dose of sorbent (C) and Cu (II) concentration (D) influenced removal efficiency at 5% significance level. Also, some interactions such as ABCD, ACD, ABC and AC affected the removal process. The sorbent was characterized with FTIR, SEM and TG/DSC. Freundlich isotherm model was the best isotherm model. The kinetic study results correlated well with the pseudo-second-order model. The thermodynamic studies revealed that the nature of copper sorption was spontaneous and endothermic. Strong affinity of the sorbent for copper (II) was revealed by the Isothermal Titration Calorimetry (ITC) technique. (C) 2016 Published by Elsevier Inc.

引用

页码：154 / 163

页数：10

共 54 条

[1] Glutaraldehyde cross-linked epoxyaminated chitosan as an adsorbent for the removal and recovery of copper(II) from aqueous media [J].

Anirudhan, Thayyath Sreenivasan ;

Rijith, Sreenivasan .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 351 (1-3) :52-59

[2] Analysis of adsorption of reactive azo dye onto CuCl2 doped polyaniline using Box-Behnken design approach [J].

Bingol, Deniz ;

Veli, Sevil ;

Zor, Sibel ;

Ozdemir, Utkan .

SYNTHETIC METALS, 2012, 162 (17-18) :1566-1571

[3] Brilliant Yellow dye adsorption onto sepiolite using a full factorial design [J].

Bingol, Deniz ;

Tekin, Nalan ;

Alkan, Mahir .

APPLIED CLAY SCIENCE, 2010, 50 (03) :315-321

[4] Sorption of heavy metal ions onto carboxylate chitosan derivatives-A mini-review [J].

Boamah, Peter Osei ;

Huang, Yan ;

Hua, Mingqing ;

Zhang, Qi ;

Wu, Jingbo ;

Onumah, Jacqueline ;

Sam-Amoah, Livingstone K. ;

Boamah, Paul Osei .

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2015, 116 :113-120

[5] Removal of cadmium from aqueous solution using low molecular weight chitosan derivative [J].

Boamah, Peter Osei ;

Huang, Yan ;

Hua, Mingqing ;

Zhang, Qi ;

Liu, Yuanyuan ;

Onumah, Jacqueline ;

Wang, Wei ;

Song, Yongxiu .

CARBOHYDRATE POLYMERS, 2015, 122 :255-264

[6] Lead removal onto cross-linked low molecular weight chitosan pyruvic acid derivatives [J].

Boamah, Peter Osei ;

Zhang, Qi ;

Hua, Mingqing ;

Huang, Yan ;

Liu, Yun ;

Wang, Wei ;

Liu, Yuanyuan .

CARBOHYDRATE POLYMERS, 2014, 110 :518-527

[7] Thermodynamics of binding interactions between divalent copper and chitin fragments by isothermal titration calorimetry (ITC) [J].

Camci-Unal, Gulden ;

Pohl, Nicola L. B. .

CARBOHYDRATE POLYMERS, 2010, 81 (01) :8-13

[8] Quantitative Determination of Heavy Metal Contaminant Complexation by the Carbohydrate Polymer Chitin [J].

Camci-Unal, Gulden ;

Pohl, Nicola L. B. .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (03) :1117-1121

[9] Experimental design for the optimization of copper biosorption from aqueous solution by Aspergillus terreus [J].

Cerino-Cordova, F. J. ;

Garcia-Leon, A. M. ;

Soto-Regalado, E. ;

Sanchez-Gonzalez, M. N. ;

Lozano-Ramirez, T. ;

Garcia-Avalos, B. C. ;

Loredo-Medrano, J. A. .

JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2012, 95 :S77-S82

[10] The removal of Cu(II) and Co(II) from aqueous solutions using cross-linked chitosan - Evaluation by the factorial design methodology [J].

Cestari, Antonio R. ;

Vieira, Eunice F. S. ;

de Oliveira, Lataanderson A. ;

Bruns, Roy E. .

JOURNAL OF HAZARDOUS MATERIALS, 2007, 143 (1-2) :8-16

← 1 2 3 4 5 6 →