Bis{2-[N,N-bis(2-aminoethyl)amino]ethanaminium}-nickel(II) hexacyanidoferrate(II)

被引:2
作者
Yao, Yue-Juan [1 ]
Shu, Hui-Ming [1 ]
Du, Chuan-Qin [1 ]
Hu, Huai-Ming [1 ]
机构
[1] NW Univ Xian, Dept Chem, Xian 710069, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词
single-crystal X-ray study; T=293 K; Mean sigma(C-C)=0.003 angstrom; R factor=0.032; wR factor=0.083; data-to-parameter ratio=16.6;
D O I
10.1107/S1600536807013475
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Ni(C6H19N4)(2)][Fe(CN)(6)], the Ni2+ and Fe2+ cations are both octahedrally coordinated. The complex cations and anions, both of which are centrosymmetric, are linked by a network of N-H center dot center dot center dot N hydrogen bonds to form a three-dimensional network.
引用
收藏
页码:M1208 / M1210
页数:3
相关论文
共 13 条
[1]   Structural consequences of spin conversion in a sterically encumbered Ni(II) porphyrin [J].
Barkigia, KM ;
Nelson, NY ;
Renner, MW ;
Smith, KM ;
Fajer, J .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (41) :8643-8646
[2]   CARBENE REARRANGEMENTS OF 2-VINYLCYCLOBUTYLIDENE [J].
BRINKER, UH ;
KONIG, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (16) :4738-4739
[3]   Dithiosquarate (dtsq) complexes of nickel(II).: Syntheses and crystal structures of [Ni(phen)2(1,2-dtsq)]•3.SH2O, [Ni(phen)2(1,3-dtsq)] and [Ni(tren)(1,2-dtsq)] [phen=1,10-phenanthroline; tren=tris(2-aminoethyl)amine] [J].
Calatayud, ML ;
Sletten, J ;
Castro, I ;
Julve, M ;
Seitz, G ;
Mann, K .
INORGANICA CHIMICA ACTA, 2003, 353 :159-167
[4]  
Enraf-Nonius, 1989, CAD 4 SOFTW
[5]  
Fair C. K, 1990, MOLEN
[6]   Synthesis of homochiral tris(2-alkyl-2-aminoethyl)amine derivatives from chiral α-amino aldehydes and their application in the synthesis of water soluble chelators [J].
Hajela, SP ;
Johnson, AR ;
Xu, JD ;
Sunderland, CJ ;
Cohen, SM ;
Caulder, DL ;
Raymond, KN .
INORGANIC CHEMISTRY, 2001, 40 (13) :3208-3216
[7]   From one-dimensional chain to pentanuclear molecule. Magnetism of cyano-bridged Fe(III)-Ni(II) complexes [J].
Kou, HZ ;
Zhou, BC ;
Liao, DZ ;
Wang, RJ ;
Li, YD .
INORGANIC CHEMISTRY, 2002, 41 (25) :6887-6891
[8]   A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].
NORTH, ACT ;
PHILLIPS, DC ;
MATHEWS, FS .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&
[9]  
Razak IA, 2000, ACTA CRYSTALLOGR C, V56, P291
[10]  
Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]