Converting Alkali Lignin to Biofuels over NiO/HZSM-5 Catalysts Using a Two-Stage Reactor

被引：6

作者：

Cheng, Shouyun ^{[1
]}

Wei, Lin ^{[1
]}

Zhao, Xianhui ^{[1
]}

Julson, James ^{[1
]}

Kadis, Ethan ^{[2
]}

机构：

[1] South Dakota State Univ, Agr & Biosyst Engn Dept, 1400 North Campus Dr, Brookings, SD 57007 USA

[2] Univ Massachusetts, Chem Engn Dept, 686 North Pleasant St, Amherst, MA 01003 USA

来源：

CHEMICAL ENGINEERING & TECHNOLOGY | 2017年 / 40卷 / 06期

基金：

美国国家科学基金会;

关键词：

Alkli lignin; Biofuels; Hydrocarbons; Pyrolysis; Zeolites; BIO-OIL; HYDROCARBON BIOFUEL; RANGE HYDROCARBONS; PYROLYSIS VAPORS; HZSM-5; ZEOLITE; ZSM-5; ZEOLITES; CAMELINA OIL; CARINATA OIL; BIOMASS; NI/HZSM-5;

D O I：

10.1002/ceat.201600539

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A series of NiO/HZSM-5 catalysts were used to convert alkali lignin to hydrocarbon biofuels in a two-stage catalytic pyrolysis system. The results indicated that all NiO/HZSM-5 catalysts reduced the content of undesirable phenols, furans, and alcohols of the biofuel compared to non-catalytic treatment. The NiO/HZSM-5 catalyst with the lowest amount of NiO generated the highest biofuel yield in all catalytic treatments, and it also produced biofuel with the highest content of hydrocarbons. The emission of carbon oxides (CO and CO2) increased in the treatments with higher-NiO loading HZSM-5 due to the redox reaction between NiO and the oxygenated compounds in the bio-oil. Ni2SiO4 was generated in the used NiO/HZSM-5 catalysts during the high-temperature pyrolysis process.

引用

页码：1069 / 1077

页数：9

共 63 条

[1] PRODUCTION OF HYDROCARBONS BY CATALYTIC UPGRADING OF A FAST PYROLYSIS BIO-OIL .2. COMPARATIVE CATALYST PERFORMANCE AND REACTION PATHWAYS [J].

ADJAYE, JD ;

BAKHSHI, NN .

FUEL PROCESSING TECHNOLOGY, 1995, 45 (03) :185-202

[2]

[Anonymous], J NANOMATER, DOI DOI 10.1371/J0URNAL.P0NE.0039690

[3]

[Anonymous], 2012, ANGEW CHEM-GER EDIT, DOI DOI 10.1002/ANGE.201108306

[4] Pyrolysis of Kraft Lignin with Additives [J].

Ben, Haoxi ;

Ragauskas, Arthur J. .

ENERGY & FUELS, 2011, 25 (10) :4662-4668

[5] Development of a bifunctional Ni/HZSM-5 catalyst for converting prairie cordgrass to hydrocarbon biofuel [J].

Cheng, S. ;

Wei, L. ;

Zhao, X. .

ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2016, 38 (16) :2433-2437

[6] Application, Deactivation, and Regeneration of Heterogeneous Catalysts in Bio-Oil Upgrading [J].

Cheng, Shouyun ;

Wei, Lin ;

Zhao, Xianhui ;

Julson, James .

CATALYSTS, 2016, 6 (12)

[7] Hydrodeoxygenation of prairie cordgrass bio-oil over Ni based activated carbon synergistic catalysts combined with different metals [J].

Cheng, Shouyun ;

Wei, Lin ;

Zhao, Xianhui ;

Kadis, Ethan ;

Cao, Yuhe ;

Julson, James ;

Gu, Zhengrong .

NEW BIOTECHNOLOGY, 2016, 33 (04) :440-448

[8] Directly catalytic upgrading bio-oil vapor produced by prairie cordgrass pyrolysis over Ni/HZSM-5 using a two stage reactor [J].

Cheng, Shouyun ;

Wei, Lin ;

Zhao, Xianhui ;

Huang, Yinbin ;

Raynie, Douglas ;

Qiu, Changling ;

Kiratu, John ;

Yu, Yong .

AIMS ENERGY, 2015, 3 (02) :227-240

[9] Pyrolysis of wheat straw-derived organosolv lignin [J].

de Wild, P. J. ;

Huijgen, W. J. J. ;

Heeres, H. J. .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2012, 93 :95-103

[10] Alkaline Partial Wet Oxidation of Lignin for the Production of Carboxylic Acids [J].

Demesa, Abayneh G. ;

Laari, Arto ;

Turunen, Ilkka ;

Sillanpaa, Mika .

CHEMICAL ENGINEERING & TECHNOLOGY, 2015, 38 (12) :2270-2278

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