New polymer organogelators with L-isoleucine and L-valine as a gelation-causing segment: Organogelation by a combination of supramolecular polymer and conventional polymer

被引：14

作者：

Suzuki, Masahiro ^{[1
]}

Yanagida, Ryosuke ^{[1
]}

Setoguchi, Chiho ^{[1
]}

Shirai, Hirofusa ^{[1
]}

Hanabusa, Kenji ^{[1
]}

机构：

[1] Shinshu Univ, Grad Sch Sci & Technol, Nagano 3868567, Japan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2008年 / 46卷 / 01期

基金：

中国国家自然科学基金;

关键词：

fibers; gelation; gels; L-isoleucine; L-valine; networks; organogels; polymer organogelator; polysiloxanes; self-assembly; self-organization;

D O I：

10.1002/pola.22385

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

New polymer organogelators, which are composed of poly(ethylene glycol), poly(propylene glycol), and poly(dimethylsiloxane)s as a polymer segment and L-iso-leucine and L-valine derivatives as a gelation-causing segment, were synthesized, and their organogelation properties were examined in organic solvents and oils. These polymer organogelators formed organogels in many organic solvents and oils, and their gels were thermally stable and had a high mechanical strength. Furthermore, the effects of the polymer backbone on the organogelation is discussed using FTIR spectroscopy, field emission scanning electron microscope observation, and analysis of thermal stability and strength of the organogel. (C) 2007 Wiley Periodicals, Inc.

引用

页码：353 / 361

页数：9

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