High rate deposition of highly stable a-Si:H films using multi-hollow discharges for thin films solar cells

被引:32
作者
Nakamura, William Makoto [1 ]
Matsuzaki, Hidefumi [1 ]
Sato, Hiroshi [1 ]
Kawashima, Yuuki [1 ]
Koga, Kazunori [1 ]
Shiratani, Masaharu [1 ]
机构
[1] Kyushu Univ, Dept Elect, Fukuoka 8190395, Japan
关键词
Multi-hollow discharge plasma CVD; a-Si:H solar cell; Deposition rate; Light-induced degradation; CHEMICAL-VAPOR-DEPOSITION; AMORPHOUS-SILICON; H FILMS; FREQUENCY DISCHARGES; VOLUME FRACTION; PLASMA; CLUSTERS; GROWTH; SIH3;
D O I
10.1016/j.surfcoat.2010.07.081
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We developed a multi-hollow discharge plasma chemical vapor deposition (CVD) method to deposit a-Si:H films of high stability against light exposure for solar cell applications. This method suppresses incorporation of clusters, which are formed in discharges, into films; and such a-Si:H films without cluster incorporation show high stability against light exposure. Aiming at increasing the deposition rate, we have developed a honeycomb type electrode with more than double number of holes, and we have realized deposition of highly stable a-Si:H films of 4.7 x 10(15) cm(-3) in stabilized defect density at a rate of 3.0 nm/s and better film thickness uniformity within 5% in an area of 4 cm in diameter. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:S241 / S245
页数:5
相关论文
共 17 条
  • [1] ELECTRON SPIN RESONANCE IN AMORPHOUS SILICON, GERMANIUM, AND SILICON CARBIDE
    BRODSKY, MH
    TITLE, RS
    [J]. PHYSICAL REVIEW LETTERS, 1969, 23 (11) : 581 - &
  • [2] Green MA, 2003, NATO SCI SER II-MATH, V93, P1
  • [3] SPATIAL-DISTRIBUTION OF SIH3 RADICALS IN RF SILANE PLASMA
    ITABASHI, N
    NISHIWAKI, N
    MAGANE, M
    NAITO, S
    GOTO, T
    MATSUDA, A
    YAMADA, C
    HIROTA, E
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1990, 29 (03): : L505 - L507
  • [4] Highly stable a-Si:H films deposited by using multi-hollow plasma chemical vapor deposition
    Koga, K
    Inoue, T
    Bando, K
    Iwashita, S
    Shiratani, M
    Watanabe, Y
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2005, 44 (46-49): : L1430 - L1432
  • [5] In situ observation of nucleation and subsequent growth of clusters in silane radio frequency discharges
    Koga, K
    Matsuoka, Y
    Tanaka, K
    Shiratani, M
    Watanabe, Y
    [J]. APPLIED PHYSICS LETTERS, 2000, 77 (02) : 196 - 198
  • [6] Correlation between volume fraction of clusters incorporated into a-Si:H films and hydrogen content associated with Si-H2 bonds in the films
    Koga, K
    Kaguchi, N
    Shiratani, M
    Watanabe, Y
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2004, 22 (04): : 1536 - 1539
  • [7] Cluster-suppressed plasma chemical vapor deposition method for high quality hydrogenated amorphous silicon films
    Koga, K
    Kai, M
    Shiratani, M
    Watanabe, Y
    Shikatani, N
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 2002, 41 (2B): : L168 - L170
  • [8] Two-dimensional spatial profile of volume fraction of nanoparticles incorporated into a-Si:H films deposited by plasma CVD
    Nakamura, William Makoto
    Miyahara, Hiroomi
    Sato, Hiroshi
    Matsuzaki, Hidefumi
    Koga, Kazunori
    Shiratani, Masaharu
    [J]. IEEE TRANSACTIONS ON PLASMA SCIENCE, 2008, 36 (04) : 888 - 889
  • [9] Cluster incorporation control for a-Si: H film deposition
    Nakamura, William Makoto
    Miyahara, Hiroomi
    Koga, Kazunori
    Shiratani, Masaharu
    [J]. PROCEEDINGS OF THE 17TH INTERNATIONAL VACUUM CONGRESS/13TH INTERNATIONAL CONFERENCE ON SURFACE SCIENCE/INTERNATIONAL CONFERENCE ON NANOSCIENCE AND TECHNOLOGY, 2008, 100
  • [10] Amorphous silicon solar cells deposited at high growth rate
    Nishimoto, T
    Takai, M
    Miyahara, H
    Kondo, M
    Matsuda, A
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 299 : 1116 - 1122