PdCl2-catalyzed reduction of organic halides by triethylsilane

被引：123

作者：

Boukherroub, R

Chatgilialoglu, C

Manuel, G

机构：

[1] CNR,ICOCEA,I-40129 BOLOGNA,ITALY

[2] UNIV TOULOUSE 3,LAB HETEROCHIM FONDAMENTALE & APPL,F-31062 TOULOUSE,FRANCE

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 05期

关键词：

D O I：

10.1021/om950514k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The palladium-catalyzed dehalogenation reaction of alkyl or aryl halides with triethylsilane takes place, giving high yields under mild reaction conditions. The efficiency of the reduction is similar for organic chlorides, bromides, or iodides, and the presence of functionalities such as esters or ethers does not interfere with the outcome of the reaction.

引用

收藏

页码：1508 / 1510

页数：3

相关论文

共 30 条

[1] NEW SYNTHESIS OF PERACETYLATED 1,5-ANHYDROHEXITOLS AND 1,5-ANHYDROPENTITOLS [J].

AUGE, J ;

DAVID, S .

CARBOHYDRATE RESEARCH, 1977, 59 (01) :255-257

[2] TITANOCENE-CATALYZED REDUCTION OF ESTERS USING POLYMETHYLHYDROSILOXANE AS THE STOICHIOMETRIC REDUCTANT [J].

BARR, KJ ;

BERK, SC ;

BUCHWALD, SL .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (15) :4323-4326

[3] AN AIR-STABLE CATALYST SYSTEM FOR THE CONVERSION OF ESTERS TO ALCOHOLS [J].

BERK, SC ;

BUCHWALD, SL .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (14) :3751-3753

[4] OXIDATIVE INSERTION AS FRONTSIDE S(N)2 SUBSTITUTION - A THEORETICAL-STUDY OF THE MODEL REACTION SYSTEM PD+CH3CL [J].

BICKELHAUPT, FM ;

ZIEGLER, T ;

SCHLEYER, PV .

ORGANOMETALLICS, 1995, 14 (05) :2288-2296

[5]

BOUKHERROUB R, 1994, MAIN GROUP MET CHEM, V17, P8

[6]

BREEDEN SW, 1994, SYNLETT, P833

[7] STRUCTURAL AND CHEMICAL-PROPERTIES OF SILYL RADICALS [J].

CHATGILIALOGLU, C .

CHEMICAL REVIEWS, 1995, 95 (05) :1229-1251

[8] ORGANOSILANES AS RADICAL-BASED REDUCING AGENTS IN SYNTHESIS [J].

CHATGILIALOGLU, C .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (04) :188-194

[9] A COMMENT ON THE USE OF TRIETHYLSILANE AS A RADICAL-BASED REDUCING AGENT [J].

CHATGILIALOGLU, C ;

FERRERI, C ;

LUCARINI, M .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (01) :249-251

[10] PALLADIUM-CATALYZED REACTIONS OF TRIORGANOSILICON HYDRIDES WITH HALOCARBONS [J].

CITRON, JD ;

LYONS, JE ;

SOMMER, LH .

JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (03) :638-&