Two coumarin formhydrazide compounds as chemosensors for copper ions

被引:15
|
作者
Wu, Qianqian [1 ]
Ma, Lin [1 ]
Xu, Yongxiao [1 ]
Cao, Duxia [1 ]
Guan, Ruifang [1 ]
Liu, Zhiqiang [2 ]
Yu, Xueying [1 ]
机构
[1] Univ Jinan, Sch Mat Sci & Engn, Shandong Prov Key Lab Preparat & Measurement Bldg, Jinan 250022, Shandong, Peoples R China
[2] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
Coumarin formhydrazide; Copper ion; Chemosensor; Complex; CYANIDE; CU(II); DERIVATIVES; COMPLEXES; WATER;
D O I
10.1016/j.inoche.2016.04.017
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two coumarin formhydrazide compounds as chemosensors for copper ions have been synthesized. The compounds can recognize copper ion with obvious absorption spectral change and fluorescence decrease in aqueous solution. The detection limit of the compound with terminal diethylamino group to Cu2+ in aq.-HEPES buffer acetonitrile (3:7, v/v, pH = 7.4) with fluorescence spectra as detected signal is 0.00041 mu M. One carbonyl and amine group in one sensor molecule may complex with one copper ion to form 1:1 complex. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:7 / 9
页数:3
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