Spatially resolved solid-state reduction of graphene oxide thin films

被引:15
作者
Morant-Minana, Maria C. [1 ,2 ]
Heidler, Jonas [2 ]
Glasser, Gunnar [2 ]
Lu, Hao [2 ]
Berger, Ruediger [2 ]
Gil-Gonzalez, Nerea [3 ]
Muellen, Klaus [2 ]
de Leeuw, Dago M. [4 ]
Asadi, Kamal [2 ]
机构
[1] CIC EnergiGUNE, Parque Tecnol Alava Albert Einstein 48,ED CIC, Minano 01510, Spain
[2] Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany
[3] CEIT IK4, Paseo Manuel Lardizabal 15, San Sebastian 20018, Spain
[4] Delft Univ Technol, Kluyverweg, NL-2629 HS Delft, Netherlands
关键词
EXFOLIATED GRAPHITE OXIDE; HIGH-QUALITY GRAPHENE; ELECTROCHEMICAL REDUCTION; ELECTRONIC TRANSPORT; RAMAN-SPECTROSCOPY; LARGE-AREA; TRANSPARENT; SHEETS; DEOXYGENATION; FABRICATION;
D O I
10.1039/c8mh00895g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Re-establishment of electrical conductivity in graphene oxide (GO), the insulating form of graphene, is (partially) accomplished by reduction through high temperature treatments in a reducing atmosphere, or using strongly reducing chemicals or electrolytic processes. The reduction methods are suited for bulk graphene oxide. Spatially resolved reduction of thin films of graphene oxide is important for a wide range of applications such as in microelectronics, where an electrolyte-free, room temperature reduction process is needed. Here, we present spatially resolved solid-state reduction of graphene oxide thin films. We demonstrate that the reduction mechanism is based on electrolysis of water that is adsorbed on the graphene oxide thin film. The reduced graphene oxide thin-films show sheet resistance of only several kOhm, with weak temperature dependence. Graphene oxide can be produced on a large scale and processed using low-cost solution casting techniques. Spatially resolved re-establishment of conductivity in GO can be used in electrically controlled water permeation or in micro- and nanoelectronic applications for instance as an anti-fuse.
引用
收藏
页码:1176 / 1184
页数:9
相关论文
共 58 条
[1]   Monolayers of Biphenyl-3,4′,5-tricarboxylic Acid Formed on Cu and Ag from Solution [J].
Aitchison, Hannah ;
Lu, Hao ;
Zharnikov, Michael ;
Buck, Manfred .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (25) :14114-14125
[2]   The synthesis of graphene sheets with controlled thickness and order using surfactant-assisted electrochemical processes [J].
Alanyalioglu, Murat ;
Jose Segura, Juan ;
Oro-Sole, Judith ;
Casan-Pastor, Nieves .
CARBON, 2012, 50 (01) :142-152
[3]   Thin Film Fabrication and Simultaneous Anodic Reduction of Deposited Graphene Oxide Platelets by Electrophoretic Deposition [J].
An, Sung Jin ;
Zhu, Yanwu ;
Lee, Sun Hwa ;
Stoller, Meryl D. ;
Emilsson, Tryggvi ;
Park, Sungjin ;
Velamakanni, Aruna ;
An, Jinho ;
Ruoff, Rodney S. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (08) :1259-1263
[4]   Up-Scaling Graphene Electronics by Reproducible Metal-Graphene Contacts [J].
Asadi, Kamal ;
Timmering, Eugene C. ;
Geuns, Tom C. T. ;
Pesquera, Amaia ;
Centeno, Alba ;
Zurutuza, Amaia ;
Klootwijk, Johan H. ;
Blom, Paul W. M. ;
de Leeuw, Dago M. .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (18) :9429-9435
[5]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[6]   Monolayers of trimesic and isophthalic acid on Cu and Ag: the influence of coordination strength on adsorption geometry [J].
Cebula, Izabela ;
Lu, Hao ;
Zharnikov, Michael ;
Buck, Manfred .
CHEMICAL SCIENCE, 2013, 4 (12) :4455-4464
[7]   Fully Integrated Graphene and Carbon Nanotube Interconnects for Gigahertz High-Speed CMOS Electronics [J].
Chen, Xiangyu ;
Akinwande, Deji ;
Lee, Kyeong-Jae ;
Close, Gael F. ;
Yasuda, Shinichi ;
Paul, Bipul C. ;
Fujita, Shinobu ;
Kong, Jing ;
Wong, H. -S. Philip .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2010, 57 (11) :3137-3143
[8]   Ultralow Power Microfuses for Write-Once Read-Many Organic Memory Elements [J].
de Brito, Bianca C. ;
Smits, Edsger C. P. ;
van Hal, Paid A. ;
Geuns, Tom C. T. ;
de Boer, Bert ;
Lasance, Clemens J. M. ;
Gomes, Henrique L. ;
de Leeuw, Dago M. .
ADVANCED MATERIALS, 2008, 20 (19) :3750-+
[9]   Apparent Roughness as Indicator of (Local) Deoxygenation of Graphene Oxide [J].
den Boer, Duncan ;
Weis, Jonathan G. ;
Zuniga, Carlos A. ;
Sydlik, Stefanie A. ;
Swager, Timothy M. .
CHEMISTRY OF MATERIALS, 2014, 26 (16) :4849-4855
[10]   Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material [J].
Eda, Goki ;
Fanchini, Giovanni ;
Chhowalla, Manish .
NATURE NANOTECHNOLOGY, 2008, 3 (05) :270-274