A hydrolytically stable amino-functionalized Zinc(II) metal-organic framework containing nanocages for selective gas adsorption and luminescent sensing

被引：112

作者：

Fan, Liming ^{[1
]}

Zhao, Dongsheng ^{[1
]}

Zhang, Huihui ^{[1
]}

Wang, Feng ^{[1
]}

Li, Bei ^{[1
]}

Yang, Lulu ^{[1
]}

Deng, Yuxin ^{[1
]}

Zhang, Xiutang ^{[1
]}

机构：

[1] North Univ China, Coll Sci, Dept Chem, Taiyuan 030051, Peoples R China

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2021年 / 326卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic framework; Hydrolytically stability; Amino-functionalized; Chemosensor; Gas adsorption; COORDINATION POLYMERS; EFFICIENT SEPARATION; FLUORESCENT SENSOR; CO2; CONVERSION; ACID; MOF; REMOVAL; CAPTURE; CR2O72; ANIONS;

D O I：

10.1016/j.micromeso.2021.111396

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

To achieve the selectivity of luminescent sensing and gas separation, an unprecedented nanocages based 3D amino-functionalized MOF, {(Me2NH2)[Zn(NH2-TCB)]}n (ZnMOF) was constructed through ligand pre-design strategy. ZnMOF contains a unique 1D triple [Zn(COO)]n helix chain SBU and forms 7.89 x 11.72 x 14.79 angstrom 3 nanocages with the porosity up to 42.9%. Benefit from the outstanding thermal and chemical stabilities, the ZnMOF demonstrates considerable adsorption selectivity for CO2/CH4 and highly sensitive detectability to Cr (VI) anions and nitroimidazole/nitrofuran antibiotics in water. In addition, the high selective adsorption and sensing mechanisms were also explored. Therefore, ZnMOF is a multifunctional material in the efficient gas adsorption and separation, and the detection of Cr(VI) anions and nitroimidazole/nitrofuran antibiotics.

引用

页数：9

共 66 条

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