Semiconducting and magnetic properties of FeS-derived compounds (C2H8N2)xFeS and Ax(C2H8N2)yFeS (A = Li, Na)

被引：8

作者：

Zheng, Hui ^{[1
]}

Ding, Changhao ^{[2
]}

Xu, Han-Shu ^{[2
]}

Tang, Lulu ^{[1
]}

Liu, Huimin ^{[1
]}

Wei, Lianwei ^{[1
]}

Tang, Kaibin ^{[1
,2
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

[2] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 37期

基金：

中国国家自然科学基金;

关键词：

CRYSTAL-STRUCTURE; SUPERCONDUCTOR; INTERCALATION; ROUTE; METAL;

D O I：

10.1039/d1dt02108g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several FeS-derived intercalated compounds (C2H8N2)(x)FeS and A(x)(C2H8N2)(y)FeS (A = Li, Na) were successfully synthesized via a novel ammonothermal method. The powder X-ray diffraction (XRD) measurements reveal that the FeS intercalated samples have the same tetragonal crystal structure as the parent FeS. After intercalation, these three as-synthesized samples do not show superconductor behavior, which is confirmed by the magnetization and the electrical resistivity measurements. (C2H8N2)(x)FeS exhibits paramagnetic semiconductor behavior, while the newly synthesized A(x)(C2H8N2)(y)FeS (A = Li, Na) shows antiferromagnetic semiconductor behavior. The absence of superconductivity in these FeS-derived compounds should be closely related to the iron vacancies in the FeS layer.

引用

页码：13052 / 13058

页数：7

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