Carbon bead-supported hollow carbon nanofibers synthesized via templating method for the removal of hexavalent chromium

被引:30
作者
Mishra, Shraddha [1 ]
Verma, Nishith [1 ,2 ]
机构
[1] Indian Inst Technol, Ctr Environm Sci & Engn, Kanpur 208016, Uttar Pradesh, India
[2] Indian Inst Technol, Dept Chem Engn, Kanpur 208016, Uttar Pradesh, India
关键词
Templating method; Carbon nanofibers; Carbon beads; Adsorption; Hexavelent chromium; AQUEOUS-SOLUTION; ACTIVATED CARBON; ADSORPTION; ADSORBENTS; NANOPARTICLES; PERFORMANCE; KINETICS; MICRO;
D O I
10.1016/j.jiec.2016.02.025
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel triethanol amine-grafted hollow carbon nanofibers (CNFs), supported on carbon beads, were synthesized via templating method for the removal of hexavalent chromium (Cr(VI)) ions from water. CNFs were grown on carbon beads by chemical vapor deposition using the in situ incorporated Cr nanoparticles in the beads, as the catalyst. The beads were ultra-sonicated to remove the nanoparticles from the tip of the CNFs, thereby creating the hollow CNFs. The Cr(VI)-adsorption capacity of the material was determined to be similar to 51 mg/g at 125 ppm-initial concentration and 4.5-solution pH. Negligible interference from coexisting metal ions in water was found with the Cr(VI)-adsorption. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:346 / 354
页数:9
相关论文
共 32 条
[1]   Aqueous heavy metals removal by adsorption on amine-functionalized mesoporous silica [J].
Aguado, Jose ;
Arsuaga, Jesus M. ;
Arencibia, Amaya ;
Lindo, Montana ;
Gascon, Victoria .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 163 (01) :213-221
[2]   Synthesis, characterization of Fe3O4@glycine doped polypyrrole magnetic nanocomposites and their potential performance to remove toxic Cr(VI) [J].
Ballav, N. ;
Choi, H. J. ;
Mishra, S. B. ;
Maity, A. .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2014, 20 (06) :4085-4093
[3]   Synthesis of Cr(VI)-imprinted poly(4-vinyl pyridine-co-hydroxyethyl methacrylate) particles: Its adsorption propensity to Cr(VI) [J].
Bayramoglu, Gulay ;
Arica, M. Yakup .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 187 (1-3) :213-221
[4]   Fe-nanoparticles dispersed carbon micro and nanofibers: Surfactant-mediated preparation and application to the removal of gaseous VOCs [J].
Bikshapathi, Mekala ;
Singh, Shiv ;
Bhaduri, Bhaskar ;
Mathur, Gyanesh N. ;
Sharma, Ashutosh ;
Verma, Nishith .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2012, 399 :46-55
[5]   One-step synthesis of high capacity mesoporous Hg2+ adsorbents by non-ionic surfactant assembly [J].
Brown, J ;
Richer, R ;
Mercier, L .
MICROPOROUS AND MESOPOROUS MATERIALS, 2000, 37 (1-2) :41-48
[6]   Adsorbents based on carbon microfibers and carbon nanofibers for the removal of phenol and lead from water [J].
Chakraborty, Anindita ;
Deva, Dinesh ;
Sharma, Ashutosh ;
Verma, Nishith .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 359 (01) :228-239
[7]   A rational template carbonization method for producing [J].
Chen, Xiang Ying ;
Song, Hong ;
Zhang, Zhong Jie ;
He, Yuan Yuan .
ELECTROCHIMICA ACTA, 2014, 117 :55-61
[8]   Removal of trivalent and hexavalent chromium with aminated polyacrylonitrile fibers: performance and mechanisms [J].
Deng, SB ;
Bai, RB .
WATER RESEARCH, 2004, 38 (09) :2424-2432
[9]   Adsorption of hexavalent chromium from aqueous solutions by bio-chars obtained during biomass pyrolysis [J].
Deveci, Huseyin ;
Kar, Yakup .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2013, 19 (01) :190-196
[10]   Adsorption of Pb2+ and Cu2+ on anionic surfactant-templated amino-functionalized mesoporous silicas [J].
Hao, Shiyou ;
Zhong, Yijun ;
Pepe, Francesco ;
Zhu, Weidong .
CHEMICAL ENGINEERING JOURNAL, 2012, 189 :160-167