Mechanochemistry: The mechanical activation of covalent bonds

被引：1092
作者：
Beyer, MK
Clausen-Schaumann, H
机构：
[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany
[2] GSF Forschungszentrum Umwelt & Gesundheit GMBH, Inst Strahlenschutz, D-85764 Neuherberg, Germany
[3] Munich Univ Appl Sci, D-80335 Munich, Germany
来源：
CHEMICAL REVIEWS | 2005年 / 105卷 / 08期
关键词：
D O I：
10.1021/cr030697h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unlike other ways of chemical activation, mechanochemistry is less known. This review gives a survey of the classical works in mechanochemistry and puts the key mechanochemical phenomena into perspective with recent results from atomic force microscopy and quantum molecular dynamics simulations. Focus is on mechanochemical phenomena, where identifiable strong, covalent chemical bonds are activated by the presence of an external mechanical force.
引用
收藏
页码：2921 / 2948
页数：28
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