Macrocyclic Core Phosphorus Dendrimers Covered on the Surface by N,P Ligands

被引：11

作者：

Badetti, Elena ^{[2
]}

Franc, Gregory ^{[1
,3
]}

Majoral, Jean-Pierre ^{[1
,3
]}

Caminade, Anne-Marie ^{[1
,3
]}

Maria Sebastian, Rosa ^{[2
]}

Moreno-Manas, Marcial ^{[2
]}

机构：

[1] CNRS, LCC, F-31077 Toulouse, France

[2] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain

[3] Univ Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 07期

关键词：

Dendrimers; N; P ligands; Macrocycles; Palladium; Platinum; Nanoparticles; CYCLAM CORE; PALLADIUM COMPLEXES; CROWN-ETHERS; METAL; CATALYSTS; POLY(AMIDOAMINE); PHTHALOCYANINE; NANOPARTICLES; RECOGNITION; DERIVATIVES;

D O I：

10.1002/ejoc.201001464

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new family of dendrimers up to the third generation is synthesized starting from a 15-membered triolefinic azamacrocycle. gamma-Iminophosphane groups are anchored on the surface of the second and third generations, and their corresponding Pd-II complexes are prepared. To investigate the effect of shielding upon the coordinating ability of the macrocyclic core, the coordination with Pd-0 and Pt-0 atoms is studied. During this process, two new materials containing Pd-0 or Pt-0 nanoparticles stabilized by these dendrimers are characterized by high-resolution transmission electron microscopy, IR spectroscopy, and elemental analysis.

引用

页码：1256 / 1265

页数：10

共 87 条

[81] Dendritic hydrogen bonding receptors: enantiomerically pure dendroclefts for the selective recognition of monosaccharides [J].