Metal Complexes of Dyes, XII [1] Halfsandwich Complexes of Ruthenium, Cobalt, Rhodium, Iridium with Iminocarboxylaten from 4-(4′-Nitrophenylazo)aniline (Disperse Orange 3) or 4,4′-Diaminoazobenzene and 2-Oxocarboxylates

被引：1

作者：

Kuehlwein, Frank ^{[1
]}

Beck, Wolfgang ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 13-14期

关键词：

4-(4 '-Nitrophenylazo)aniline (Disperse Orange 3); 4,4 '-Diaminoazobenzene; 2-Iminocarboxylate; p-Cymene; Ruthenium; Cobalt; BIOLOGICALLY IMPORTANT LIGANDS; AMINO-ACID ANIONS; ARYLAZOIMIDAZOLE LIGANDS; MOLECULAR-STRUCTURE; FUSED RINGS; AZO DYES; REACTIVITY; STABILITY; IMINES; SOLVATOCHROMISM;

D O I：

10.1002/zaac.201000162

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The condensation of the amino groups of 4-(4'-nitrophenylazo) aniline or of 4,4'-diaminoazo-benzene with 2-oxocarboxylates at chlorido bridged half-sandwich complexes [(C5Me5)MCl2](2) (M = Rh, Ir), [(p-cymene) RuCl2](2) or of [(C5Me5)(Co(CO)I-2] provides a convenient way to attach azodyes to a metal ion via an 2-iminocarboxylate ligand.

引用

页码：2323 / 2328

页数：6

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[1]

[Anonymous], COMPREHENSIVE ORGANO

[2]

[Anonymous], COMPREHENSIVE ORGANO

[3]

[Anonymous], 1973, ORG SYNTH, V5, P341

[4] INDIGO-METAL COMPLEXES - SYNTHESIS AND STRUCTURE OF PDII AND PTII COMPOUNDS CONTAINING THE ANIONS OF INDIGO AND OCTAHYDROINDIGO AS MONO- AND BIS-CHELATE LIGANDS [J].