Fabricating a Mn3O4/Ni(OH)2 Nanocomposite by Water-Boiling Treatment for Use in Asymmetric Supercapacitors as an Electrode Material

被引:33
作者
He, Qan-Qan [1 ]
Wang, Hong-Yan [1 ]
Lun, Ning [1 ]
Qi, Yong-Xin [1 ]
Liu, Jiu-Rong [1 ]
Feng, Jin-Kui [1 ]
Qiu, Jun [2 ]
Bai, Yu Jun [1 ]
机构
[1] Shandong Univ, Minist Educ, Key Lab Liquid Solid Struct Evolut & Proc Mat, 17923 Jingshi Rd, Jinan 250061, Shandong, Peoples R China
[2] Shandong Univ Sci & Technol, Sch Chem & Environm Engn, Qingdao 266590, Shandong, Peoples R China
来源
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 11期
关键词
Supercapacitor; Water-boiling treatment; Asymmetric capacitor; Ni(OH)(2); Mn3O4; DOUBLE HYDROXIDE NANOSHEETS; MANGANESE-DIOXIDE; FACILE SYNTHESIS; NICKEL-OXIDE; ELECTROCHEMICAL PERFORMANCE; ENERGY-STORAGE; THIN-FILMS; CARBON; MNO2; COMPOSITE;
D O I
10.1021/acssuschemeng.8b04195
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrode material is the key factor for developing asymmetric supercapacitors. A simple water-boiling treatment was adopted to fabricate a Mn3O4/Ni(OH)(2) nanocomposite on a large scale, which exhibited a splendid electrochemical performance with a boiling time of 3 h, achieving a capacitance of 742 F g(-1) at 1 A g(-1). When assembling the asymmetric capacitor with the Mn3O4/Ni(OH)(2) composite and activated carbon separately as positive and negative electrodes, a capacitance of 43 F g(-1) was attained at 0.2 A g(-1) with an energy density of 15.3 Wh kg(-1) at a power density of 168.8 W kg(-1). This simple, reproducible, ecofriendly, and large-scale fabrication method is practical for preparing other transition metal oxides for the purpose of use in asymmetric supercapacitors with superior properties.
引用
收藏
页码:15688 / +
页数:17
相关论文
共 63 条
  • [1] [Anonymous], 2017, APPL SURF SCI, V403, P601, DOI DOI 10.1016/J.APSUSC.2017.01.236
  • [2] PANI/DBSA/H2SO4: A promising and highly efficient electrode material for aqueous supercapacitors
    Bilal, Salma
    Begum, Bushra
    Gul, Salma
    Shah, Anwar-ul-Haq Ali
    [J]. SYNTHETIC METALS, 2018, 235 : 1 - 15
  • [3] Porous Nickel Hydroxide Manganese Dioxide-Reduced Graphene Oxide Ternary Hybrid Spheres as Excellent Supercapacitor Electrode Materials
    Chen, Hao
    Zhou, Shuxue
    Wu, Limin
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (11) : 8621 - 8630
  • [4] Chemical synthesis and characterization of Mn3O4 thin films for supercapacitor application
    Dubal, D. P.
    Dhawale, D. S.
    Salunkhe, R. R.
    Fulari, V. J.
    Lokhande, C. D.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 497 (1-2) : 166 - 170
  • [5] Development of hybrid materials based on sponge supported reduced graphene oxide and transition metal hydroxides for hybrid energy storage devices
    Dubal, Deepak P.
    Holze, Rudolf
    Gomez-Romero, Pedro
    [J]. SCIENTIFIC REPORTS, 2014, 4
  • [6] Porous polypyrrole clusters prepared by electropolymerization for a high performance supercapacitor
    Dubal, Deepak P.
    Lee, Sang Ho
    Kim, Jong Guk
    Kim, Won Bae
    Lokhande, Chandrakant D.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (07) : 3044 - 3052
  • [7] Monodispersed plum candy-like MnO2 nanosheets-decorated NiO nanostructures for supercapacitors
    Guo, Xiao Long
    Kuang, Min
    Dong, Fan
    Zhang, Yu Xin
    [J]. CERAMICS INTERNATIONAL, 2016, 42 (06) : 7787 - 7792
  • [8] Nickel-Manganese Layered Double Hydroxide Nanosheets Supported on Nickel Foam for High-performance Supercapacitor Electrode Materials
    Guo, Xiao Long
    Liu, Xiao Ying
    Hao, Xiao Dong
    Zhu, Shi Jin
    Dong, Fan
    Wen, Zhong Quan
    Zhang, Yu Xin
    [J]. ELECTROCHIMICA ACTA, 2016, 194 : 179 - 186
  • [9] Controllable preparation of graphene/MnO2/Co3O4 for supercapacitors
    Han, Linxiu
    Xu, Zhenfu
    Wu, Jie
    Guo, Xueqi
    Zhu, Huiling
    Cui, Hongzhi
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 729 : 1183 - 1189
  • [10] Capacitance decay of nano porous nickel hydroxide
    Hu, Guangxia
    Li, Chunxiang
    Gong, Hao
    [J]. JOURNAL OF POWER SOURCES, 2010, 195 (19) : 6977 - 6981