Donor-functionalised N-heterocyclic carbene complexes of group 9 and 10 metals in catalysis: Trends and directions

被引:366
作者
Normand, Adrien T. [1 ]
Cavell, Kingsley J. [1 ]
机构
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, England
关键词
N-heterocyclic carbenes; functionalised ligands; homogeneous catalysis;
D O I
10.1002/ejic.200800323
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review focuses on the latest advances in homogeneous catalysis with donor-functionalised (donor = C, N, O, S or P) N-heterocyclic carbene complexes of group 9 and 10 metals. The applications of such complexes to C-C coupling reactions, alkyne and ketone hydrosilylation, olefin polymerisation, transfer hydrogenation, asymmetric hydrogenation and other catalysed reactions are discussed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
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页码:2781 / 2800
页数:20
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