Donor-functionalised N-heterocyclic carbene complexes of group 9 and 10 metals in catalysis: Trends and directions

被引:366
作者
Normand, Adrien T. [1 ]
Cavell, Kingsley J. [1 ]
机构
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, England
关键词
N-heterocyclic carbenes; functionalised ligands; homogeneous catalysis;
D O I
10.1002/ejic.200800323
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review focuses on the latest advances in homogeneous catalysis with donor-functionalised (donor = C, N, O, S or P) N-heterocyclic carbene complexes of group 9 and 10 metals. The applications of such complexes to C-C coupling reactions, alkyne and ketone hydrosilylation, olefin polymerisation, transfer hydrogenation, asymmetric hydrogenation and other catalysed reactions are discussed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
引用
收藏
页码:2781 / 2800
页数:20
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共 188 条
[1]   Detour-free synthesis of platinum-bis-NHC chloride complexes, their structure and catalytic activity in the CH activation of methane [J].
Ahrens, Sebastian ;
Strassner, Thomas .
INORGANICA CHIMICA ACTA, 2006, 359 (15) :4789-4796
[2]   Chelating bis-carbene rhodium(III) complexes in transfer hydrogenation of ketones and imines [J].
Albrecht, M ;
Crabtree, RH ;
Mata, J ;
Peris, E .
CHEMICAL COMMUNICATIONS, 2002, (01) :32-33
[3]   Chelated iridium(III) bis-carbene complexes as air-stable catalysts for transfer hydrogenation [J].
Albrecht, M ;
Miecznikowski, JR ;
Samuel, A ;
Faller, JW ;
Crabtree, RH .
ORGANOMETALLICS, 2002, 21 (17) :3596-3604
[4]   Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex: Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes [J].
Andavan, GTS ;
Bauer, EB ;
Letko, CS ;
Hollis, TK ;
Tham, FS .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (24-25) :5938-5947
[5]   A STABLE CRYSTALLINE CARBENE [J].
ARDUENGO, AJ ;
HARLOW, RL ;
KLINE, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) :361-363
[6]   ELECTRONIC STABILIZATION OF NUCLEOPHILIC CARBENES [J].
ARDUENGO, AJ ;
DIAS, HVR ;
HARLOW, RL ;
KLINE, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) :5530-5534
[7]   Palladium, rhodium and platinum complexes of ortho-xylyl-linked bis-N-heterocyclic carbenes:: Synthesis, structure and catalytic activity [J].
Baker, Murray V. ;
Brown, David H. ;
Simpson, Peter V. ;
Skelton, Brian W. ;
White, Allan H. ;
Williams, Charlotte C. .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (26) :5845-5855
[8]   Palladium carbene complexes derived from imidazolium-linked ortho-cyclophanes [J].
Baker, MV ;
Skelton, BW ;
White, AH ;
Williams, CC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (02) :111-120
[9]   Imidazolium-linked cyclophanes [J].
Baker, MV ;
Bosnich, MJ ;
Williams, CC ;
Skelton, BW ;
White, AH .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1999, 52 (09) :823-825
[10]   Synthesis and application of complexes of a novel chiral diphenylphosphino-functionalized N-heterocyclic carbene [J].
Bappert, E ;
Helmchen, G .
SYNLETT, 2004, (10) :1789-1793