Self-assembly of a Cu(II)-Ba(II) 2D coordination polymer containing decanuclear 28-membered metallocycles

被引：9

作者：

Liu, WL ^{[1
]}

Zou, Y ^{[1
]}

Lu, CS ^{[1
]}

Ni, CL ^{[1
]}

Dang, DB ^{[1
]}

Li, YZ ^{[1
]}

Meng, QJ ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 03期

基金：

中国国家自然科学基金;

关键词：

metalloligand; heterometallic macrocycle; copper-barium; dipeptide; crystal structure;

D O I：

10.1016/j.inoche.2004.01.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel heterometallic 2D coordination polymer, {[Ba(H2O)(4)(CuL)(2)]}(infinity) (1) (H3L = N-2-hydroxyacetophenoneglycylglycine), was synthesized by self-assembly between metalloligands [CuL](-) and the Ba(II) ions. The structure reveals the polymer contains hexanuclear building blocks, which are connected to form 28-membered decanuclear metallocycles, and are assembled further into 2D network structure. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：434 / 436

页数：3

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