Catalytic Hydrogenation of Carbon Dioxide and Bicarbonates with a Well-Defined Cobalt Dihydrogen Complex

被引：230

作者：

Federsel, Christopher ^{[1
]}

Ziebart, Carolin ^{[1
]}

Jackstell, Ralf ^{[1
]}

Baumann, Wolfgang ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 01期

关键词：

atmospheric chemistry; carbon dioxide fixation; cobalt; hydrogenation; reduction; HOMOGENEOUS CATALYSTS; ALKYL FORMATES; FORMIC-ACID; IRON; ACTIVATION; METAL; CO2; HYDROSILYLATION; EPOXIDATION; CONVERSION;

D O I：

10.1002/chem.201101343

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Co)balt upright: A well-defined cobalt dihydrogen complex is shown to be an active catalyst for the hydrogenation of CO 2 and bicarbonates (see figure), giving the highest turnover numbers so far for any non-precious-metal-based catalyst. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：72 / 75

页数：4

共 44 条

[1] Chemo- and Stereoselective Iron-Catalyzed Hydrosilylation of Ketones [J].

Addis, Daniele ;

Shaikh, Nadim ;

Zhou, Shaolin ;

Das, Shoubhik ;

Junge, Kathrin ;

Beller, Matthius .

CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (07) :1687-1691

[2] Complexes [(P-2)Rh(hfacac)] as model compounds for the fragment [(P-2)Rh] and as highly active catalysts for CO2 hydrogenation: The accessible molecular surface (AMS) model as an approach to quantifying the intrinsic steric properties of chelating ligands in homogeneous catalysis [J].

Angermund, K ;

Baumann, W ;

Dinjus, E ;

Fornika, R ;

Gorls, H ;

Kessler, M ;

Kruger, C ;

Leitner, W ;

Lutz, F .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (05) :755-764

[3]

[Anonymous], 2010, ANGEW CHE, DOI DOI 10.1002/ANGE.201004263

[4] HYDROCONDENSATION OF CO2 .2. REACTION OF CARBON-DIOXIDE AND CARBON-MONOXIDE WITH [HCUPPH3]6 [J].

BEGUIN, B ;

DENISE, B ;

SNEEDEN, RPA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 208 (01) :C18-C20

[5] A STABLE ETA-2-H-2 COMPLEX OF COBALT - ROLE OF THE H-H INTERACTION IN HYDROGEN TRANSFER FROM METAL TO ALKENE [J].

BIANCHINI, C ;

MEALLI, C ;

MELI, A ;

PERUZZINI, M ;

ZANOBINI, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (26) :8725-8726

[6] Iron-Catalyzed Hydrogen Production from Formic Acid [J].

Boddien, Albert ;

Loges, Bjorn ;

Gaertner, Felix ;

Torborg, Christian ;

Fumino, Koichi ;

Junge, Henrik ;

Ludwig, Ralf ;

Beller, Matthias .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :8924-8934

[7] A Mercurial Route to a Cobalt Dihydrogen Complex [J].

Bullock, R. Morris .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (18) :4050-4052

[8]

BURGEMEISTER T, 1993, ANGEW CHEM INT EDIT, V32, P739, DOI 10.1002/anie.199307391

[9]

Burgemeister T., 1993, ANGEW CHEM, V105, P781

[10] Iron-catalysed carbon-heteroatom and heteroatom-heteroatom bond forming processes [J].

Correa, Arkaitz ;

Mancheno, Olga Garcia ;

Bolm, Carsten .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (06) :1108-1117

← 1 2 3 4 5 →