Visible-Light Driven Hydrolysis of Benzyl Halides with Water for Preparation of Benzyl Alcohols

被引:15
作者
Xu, Jianbin [1 ]
Liu, Na [1 ]
Zou, Lingling [2 ]
Cheng, Feixiang [1 ]
Shen, Xianfu [1 ]
Liu, Teng [1 ]
Lv, Haiping [2 ]
Khan, Ruhima [2 ]
Fan, Baomin [2 ]
机构
[1] Qujing Normal Univ, Yunnan Guizhou Plateau Chem Funct Mat Pollut Cont, Qujing 655011, Peoples R China
[2] Yunnan Minzu Univ, Key Lab Chem Ethn Med Resources, YMU HKBU Joint Lab Tradit Nat Med, Kunming 650500, Yunnan, Peoples R China
关键词
hydrolysis reaction; visible light; benzyl halides; benzyl alcohols; photocatalysis; AROMATIZATION REACTION CASCADE; PHOTOREDOX CATALYSIS; SELECTIVE METHOD; METAL-FREE; HYDROGENATION; OXIDATION; LIGANDS; MILD; BENZALDEHYDE; CYCLIZATION;
D O I
10.1002/ajoc.201800658
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Visible-light-mediated hydrolysis of benzyl halides has been achieved that is efficiently catalyzed by metal-free catalyst rhodamine B. Benzyl bromides and chlorides can smoothly react with water to prepare a series of benzyl alcohol compounds in good yields.
引用
收藏
页码:261 / 264
页数:4
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