Ionothermal Synthesis of Carbon/TiO2 Nanocomposite for Supercapacitors

被引：40

作者：

Tao, Runming ^{[1
,2
,3
]}

Wang, Tao ^{[2
]}

Fan, Juntian ^{[1
]}

Meyer, Harry M. ^{[4
]}

Borisevich, Albina Y. ^{[4
]}

Chi-Linh Do-Thanh ^{[1
]}

Dai, Sheng ^{[1
,2
]}

机构：

[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[2] Oak Ridge Natl Lab, Chem Sci Div, Oak Ridge, TN 37830 USA

[3] Oak Ridge Natl Lab, Electrificat & Energy Infrastruct Div, Oak Ridge, TN 37831 USA

[4] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA

来源：

CHEMNANOMAT | 2022年 / 8卷 / 04期

关键词：

ionothermal synthesis; ionic liquid; TiO2; porous material; supercapacitor; LITHIUM-ION BATTERIES; ELECTROCHEMICAL SUPERCAPACITORS; LIQUIDS; TIO2; PERFORMANCE; GRAPHENE; NITRIDE; ANATASE; ELECTRODES; INSIGHTS;

D O I：

10.1002/cnma.202200075

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile in-situ ionothermal strategy is designed to synthesize carbon/oxide composites with nanoporous structure. Ionic liquids play key roles in this ionothermal method as the solvents, porous structure directing templates and carbon sources. The interaction between ionic liquids and oxides greatly improves the carbon yield of ionic liquids from nearly 0 to 18 wt.%. With the synergistic effects of the high electrical conductivity of the nitrogen-rich carbon species and the Ti3+ self-doping enhanced electrical conductivity of TiO2, C/TiO2-4 composite exhibits better electrochemical performance than C/SiO2 and C/Nb2O5 do as a supercapacitor electrode material, delivering a high specific capacitance of 152.4 F g(-1) at 5 mV s(-1) with good capacitance retentions of 84.7%, 72.2% and 46.0% at 30, 100 and 500 mV s(-1), respectively.

引用

页数：8

共 51 条

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