Synthesis of hexabenzocoronene-layered compounds

被引：6

作者：

Nakano, Tatsuya ^{[1
]}

Morisaki, Yasuhiro ^{[1
]}

Chujo, Yoshiki ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 16期

关键词：

Hexabenzocoronene; pi-pi stacking; Xanthene; SPACE CONJUGATED POLYMERS; MOLECULAR-ORBITAL METHODS; HEXA-PERI-HEXABENZOCORONENE; GAUSSIAN-TYPE BASIS; PI-STACKED POLYMER; ELECTROCHEMICAL POLYMERIZATION; OPTICAL-PROPERTIES; 3RD-ROW ATOMS; BASIS-SETS; OLIGOMERS;

D O I：

10.1016/j.tetlet.2015.03.026

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report herein the synthesis and properties of it-stacked dimeric and polymeric compounds that consisted of hexabenzocoronene (HBC) and xanthene as the stacked pi-electron system and the scaffold, respectively; the compounds were obtained by Sonogashira-Hagihara coupling. The obtained polymer was separated into three fractions, and the through-space conjugation effect was estimated. HBC units were layered in proximity (approximately 3.4 angstrom), leading to pi-pi stacking in the ground and excited states. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：2086 / 2090

页数：5

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