The elastic modulus of pure and doped ceria

被引:52
作者
Wachtel, Ellen [1 ]
Lubomirsky, Igor [1 ]
机构
[1] Weizmann Inst Sci, Dept Mat & Interfaces, IL-76100 Rehovot, Israel
关键词
Solid oxide fuel cells; Gd-doped ceria; Elastic properties; Chemistry of point defects; MECHANICAL-PROPERTIES; FRACTURE PROPERTIES; THERMAL-EXPANSION; POINT-DEFECTS; ELECTROLYTES; CONDUCTIVITY; SOLIDS;
D O I
10.1016/j.scriptamat.2010.09.021
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Measurements of the elastic modulus of pure and doped ceria are summarized from the literature and analyzed with a view towards understanding the experimentally established dependence on temperature, doping level and oxygen vacancy concentration. At least two chemical properties affect the elastic modulus of pure and doped ceria: (i) the presence of vacancies decreases the strength of the chemical bonds; and (ii) low-temperature adaptation of the fluorite structure to the presence of oxygen vacancies is accompanied by an increase in unit cell volume. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:112 / 117
页数:6
相关论文
共 32 条
[1]   Mechanical behaviour of ceramic oxygen ion-conducting membranes [J].
Atkinson, A ;
Selçuk, A .
SOLID STATE IONICS, 2000, 134 (1-2) :59-66
[2]   Defect equilibria and chemical expansion in non-stoichiometric undoped and gadolinium-doped cerium oxide [J].
Bishop, S. R. ;
Duncan, K. L. ;
Wachsman, E. D. .
ELECTROCHIMICA ACTA, 2009, 54 (05) :1436-1443
[3]   Electrical and mechanical properties of CeO2-based electrolytes in the CeO2-Sm2O3-M2O3 (M=La,Y) system [J].
Dudek, Magdalena ;
Bogusz, Wladyslaw ;
Zych, Lukasz ;
Trybalska, Barabara .
SOLID STATE IONICS, 2008, 179 (1-6) :164-167
[4]   The role of point defects in the physical properties of nonstoichiometric ceria [J].
Duncan, Keith L. ;
Wang, Yanli ;
Bishop, Sean R. ;
Ebrahimi, Fereshteh ;
Wachsman, Eric D. .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (04)
[5]   Role of point defects in the physical properties of fluorite oxides [J].
Duncan, Keith L. ;
Wang, Yanli ;
Bishop, Sean R. ;
Ebrahimi, Fereshteh ;
Wachsman, Eric D. .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (10) :3162-3166
[6]   Review on microfabricated micro-solid oxide fuel cell membranes [J].
Evans, Anna ;
Bieberle-Huetter, Anja ;
Rupp, Jennifer L. M. ;
Gauckler, Ludwig J. .
JOURNAL OF POWER SOURCES, 2009, 194 (01) :119-129
[7]   Solid oxide fuel cells: Systems and materials [J].
Gauckler, LJ ;
Beckel, D ;
Buergler, BE ;
Jud, E ;
Muecke, UR ;
Prestat, M ;
Rupp, JLM ;
Richter, J .
CHIMIA, 2004, 58 (12) :837-850
[8]   Interpretations of indentation size effects [J].
Gerberich, WW ;
Tymiak, NI ;
Grunlan, JC ;
Horstemeyer, MF ;
Baskes, MI .
JOURNAL OF APPLIED MECHANICS-TRANSACTIONS OF THE ASME, 2002, 69 (04) :433-442
[9]   Elasticity of solids with a large concentration of point defects [J].
Greenberg, M ;
Wachtel, E ;
Lubomirsky, I ;
Fleig, J ;
Maier, J .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (01) :48-52
[10]   Thermal expansion of Gd-doped ceria and reduced ceria [J].
Hayashi, H ;
Kanoh, M ;
Quan, CJ ;
Inaba, H ;
Wang, SR ;
Dokiya, M ;
Tagawa, H .
SOLID STATE IONICS, 2000, 132 (3-4) :227-233