IR Absorption, Raman Scattering, and IR-Vis Sum-Frequency Generation Spectroscopy as Quantitative Probes of Surface Structure

被引:28
作者
Hung, Kuo-Kai [1 ]
Stege, Ulrike [1 ]
Hore, Dennis K. [2 ]
机构
[1] Univ Victoria, Dept Comp Sci, Victoria, BC V8W 3V6, Canada
[2] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Molecular orientation; surface structure; infrared absorption; Raman Scattering; visible-infrared sum-frequency generation; VIBRATIONAL SPECTROSCOPY; MOLECULAR-ORIENTATION; 2ND-HARMONIC GENERATION; WATER-MOLECULES; NONLINEAR SPECTROSCOPY; CHARGED INTERFACE; LIQUID INTERFACES; POLYMER SURFACES; ORDER PARAMETERS; POLARIZATION;
D O I
10.1080/05704928.2014.986736
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Vibrational spectroscopy is a valuable quantitative tool for the determination of structure at surfaces. Various techniques may be applicable and useful, depending on what is available, the transparency of the substrates, the need for in situ probes, and the degree of interfacial specificity required. We examine and compare signals in infrared absorption, Raman scattering, and vibrational sum-frequency generation spectroscopy to the underlying molecular response. In all of these experiments, varying the beam polarizations enables the orientation of specific chemical functional groups to be determined. However, the sensitivity of each technique is directly connected to the manner in which the molecular response manifests itself in the measured signal. Starting with simple distributions of a single vibrational mode, leading up to multiple vibrational bands in more complex orientation distributions, we compare these three techniques in terms of their sensitivity to features of the molecular orientation distribution. This review is aimed at guiding planned experiments when multiple techniques are available for surface structural analysis.
引用
收藏
页码:351 / 376
页数:26
相关论文
共 41 条
[21]   Molecular surface structure of comb-like polyoxyethylene with alkyl sulfonyl side-chains studied by sum-frequency generation vibrational spectroscopy [J].
Seo, Inseon ;
Sohn, Eun-Ho ;
Lee, Jong-Chan ;
Song, Kigook ;
Araoka, Fumito ;
Ishikawa, Ken ;
Takezoe, Hideo .
LIQUID CRYSTALS, 2012, 39 (03) :323-331
[22]   Observation of gold electrode surface response to the adsorption and oxidation of thiocyanate in acidic electrolyte with broadband sum-frequency generation spectroscopy [J].
Wang, Jingjing ;
Xu, Mei ;
Huangfu, Zhichao ;
Wang, Ying ;
He, Yuhan ;
Guo, Wei ;
Wang, Zhaohui .
VIBRATIONAL SPECTROSCOPY, 2016, 85 :122-127
[23]   Electronic Structure of the CO/Pt(111) Electrode Interface Probed by Potential-Dependent IR/Visible Double Resonance Sum Frequency Generation Spectroscopy [J].
Yang, Shuo ;
Noguchi, Hidenori ;
Uosaki, Kohei .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (46) :26056-26063
[24]   Nonlinear optical response of a gold surface in the visible range: A study by two-color sum-frequency generation spectroscopy. II. Model for metal nonlinear susceptibility [J].
Busson, B. ;
Dalstein, L. .
JOURNAL OF CHEMICAL PHYSICS, 2018, 149 (03)
[25]   Quantitative Surface Chirality Detection with Sum Frequency Generation Vibrational Spectroscopy: Twin Polarization Angle Approach [J].
Wei, Feng ;
Xu, Yan-yan ;
Guo, Yuan ;
Liu, Shi-lin ;
Wang, Hong-fei .
CHINESE JOURNAL OF CHEMICAL PHYSICS, 2009, 22 (06) :592-600
[26]   Surface chemistry-mechanical property relationship of low density polyethylene: an IR plus visible sum frequency generation spectroscopy and atomic force microscopy study [J].
Gracias, D. H. ;
Zhang, D. ;
Shen, Y. R. ;
Somorjai, G. A. .
TRIBOLOGY LETTERS, 1998, 4 (3-4) :231-235
[27]   Surface chemistry-mechanical property relationship of low density polyethylene: an IR+visible sum frequency generation spectroscopy and atomic force microscopy study [J].
D.H. Gracias ;
D. Zhang ;
Y.R. Shen ;
G.A. Somorjai .
Tribology Letters, 1998, 4 :231-235
[28]   Dependence of the Surface Structure of Polystyrene on Chain Molecular Weight Investigated by Sum Frequency Generation Spectroscopy [J].
Bzeih, Wasef ;
Gheribi, Amara ;
Wood-Adams, Paula M. ;
Hayes, Patrick L. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (07) :3838-3845
[29]   Probing the Molecular Structure and Dynamics of Membrane-Bound Proteins during Misfolding Processes by Sum-Frequency Generation Vibrational Spectroscopy [J].
Zheng, Xiaoxuan ;
Ni, Zijian ;
Pei, Quanbing ;
Wang, Mengmeng ;
Tan, Junjun ;
Bai, Shiyu ;
Shi, Fangwen ;
Ye, Shuji .
CHEMPLUSCHEM, 2024, 89 (06)
[30]   First-principles study on sum-frequency generation spectroscopy of methanol adsorbed on TiO2(110) surface: Effects of substrate and molecular coverages [J].
Shen, Zhitao ;
Lin, Chih-Kai ;
Zhu, Chaoyuan ;
Lin, Sheng Hsien .
JOURNAL OF CHEMICAL PHYSICS, 2019, 150 (18)